Products comprising malodor reduction materials

ABSTRACT

The present invention relates to products that comprise malodor reduction compositions and methods of making and using such products. Such malodor reduction compositions do not unduly interfere with the scent of the perfumed or unperfumed products comprising such malodor reduction compositions and the perfumed or unperfumed situs that is treated with such products.

FIELD OF THE INVENTION

The present invention relates to products that comprise malodorreduction compositions and methods of making and using such solidconsumer products.

BACKGROUND OF THE INVENTION

Unscented or scented products are desired by consumers as they may beconsidered more natural and discreet than scented products.Manufacturers of unscented or scented products for controlling malodorsrely on malodor reduction ingredients or other technologies (e.g.filters) to reduce malodors. However, effectively controlling malodors,for example, amine-based malodors (e.g. fish and urine), thiol andsulfide-based malodors (e.g. garlic and onion), C₂-C₁₂ carboxylic acidbased malodors (e.g. body and pet odor), indole based malodors (e.g.fecal and bad breath), short chain fatty aldehyde based malodors (e.g.grease) and geosmin based malodors (e.g. mold/mildew) may be difficult,and the time required for a product to noticeably reduce malodors maycreate consumer doubt as to the product's efficacy on malodors. Oftentimes, manufacturers incorporate scented perfumes to help mask thesedifficult malodors.

Unfortunately, malodor control technologies typically cover up themalodor with a stronger scent and thus interfere with the scent of theperfumed or unperfumed situs that is treated with the malodor controltechnology. Thus, limited nature of the current malodor controltechnologies is extremely constraining. Thus what is needed is a broaderpalette of malodor control technologies so the perfume community candeliver the desired level of character in a greater number ofsituations/applications. Surprisingly, Applicants recognized that inaddition to blocking a malodor's access to a sensory cell, in order toachieve the desired goal, a malodor control technology must leave suchsensor cell open to other molecules, for example scent molecules. As aresult, such malodor reduction compositions do not unduly interfere withthe scent of the perfumed or unperfumed products and the perfumed orunperfumed situs that is treated with the products comprising suchmalodor control technology.

SUMMARY OF THE INVENTION

The present invention relates to products that comprise malodorreduction compositions and methods of making and using such products.Such malodor reduction compositions do not unduly interfere with thescent of the perfumed or unperfumed products comprising such malodorreduction compositions and the perfumed or unperfumed situs that istreated with such products.

DETAILED DESCRIPTION OF THE INVENTION

As used herein “MORV” is the calculated malodor reduction value for asubject material. A material's MORV indicates such material's ability todecrease or even eliminate the perception of one or more malodors. Forpurposes of the present application, a material's MORV is calculated inaccordance with method found in the test methods section of the presentapplication.

As used herein, the term “perfume” does not include malodor reductionmaterials. Thus, the perfume portion of a composition does not include,when determining the perfume's composition, any malodor reductionmaterials found in the composition as such malodor reduction materialsare described herein. In short, if a material has a malodor reductionvalue “MORV” that is within the range of the MORV recited in the subjectclaim, such material is a malodor reduction material for purposes ofsuch claim.

As used herein “consumer product” means a solid composition forcleaning, treating, and enhancing fabrics

As used herein, “malodor” refers to compounds generally offensive orunpleasant to most people, such as the complex odors associated withbowel movements.

As used herein, “odor blocking” refers to the ability of a compound todull the human sense of smell.

As used herein, the terms “a” and “an” mean “at least one”.

As used herein, the terms “include”, “includes” and “including” aremeant to be non-limiting.

Unless otherwise noted, all component or composition levels are inreference to the active portion of that component or composition, andare exclusive of impurities, for example, residual solvents orby-products, which may be present in commercially available sources ofsuch components or compositions.

All percentages and ratios are calculated by weight unless otherwiseindicated. All percentages and ratios are calculated based on the totalcomposition unless otherwise indicated.

It should be understood that every maximum numerical limitation giventhroughout this specification includes every lower numerical limitation,as if such lower numerical limitations were expressly written herein.Every minimum numerical limitation given throughout this specificationwill include every higher numerical limitation, as if such highernumerical limitations were expressly written herein. Every numericalrange given throughout this specification will include every narrowernumerical range that falls within such broader numerical range, as ifsuch narrower numerical ranges were all expressly written herein.

Malodor Reduction Materials

A non-limiting set of suitable malodor reduction materials are providedin the tables below. For ease of use, each material in Tables 1-3 isassigned a numerical indentifier which is found in the column for eachtable that is designated Number. Table 4 is a subset of Table 1, Table 5is a subset of Table 2 and Table 6 is a subset of Table 3 and there forTables 4, 5 and 6 each use the same numerical identifier as found,respectively, in Tables 1-3.

Codes A = Vapor Pressure >0.1 torr B = Vapor Pressure is between 0.01torr and 0.1 torr C = logP <3 D = logP >3 E = Probability of IngredientColor Instability = 0% F = Probability of Ingredient Color Instability<71% G = Odor Detection Threshold less than p.ol = 8 H = Odor DetectionThreshold greater than p.ol = 8 I = Melamine formaldehyde PMC HeadspaceResponse Ratio greater than or equal to 10 J = Melamine formaldehyde PMCleakage less than or equal to 5% K = Log of liquid dish neat productliquid-air partition coefficient greater than or equal to −7 L = Log ofliquid dish neat product liquid-air partition coefficient greater thanor equal to −5

TABLE 1 List of materials with at least one MORV from 1 to 5 NumberMaterial Name CAS Number Comment Code 1 2-ethylhexyl (Z)-3-(4- 5466-77-3DEFHJ methoxyphenyl)acrylate 2 2,4-dimethyl-2-(5,5,8,8-tetramethyl-131812-67-4 DFHJ 5,6,7,8-tetrahydronaphthalen-2-yl)- 1,3-dioxolane 31,1-dimethoxynon-2-yne 13257-44-8 ACEFHJK 4 para-Cymen-8-ol 1197-01-9BCGIJK 7 3-methoxy-7,7-dimethyl-10- 216970-21-7 BDEFHJKmethylenebicyclo[4.3.1]decane 9 Methoxycyclododecane 2986-54-1 DEFHJK 101,1-dimethoxycyclododecane 950-33-4 DEFHJK 11 (Z)-tridec-2-enenitrile22629-49-8 DEFHJK 13 Oxybenzone 131-57-7 DEFGJ 14 Oxyoctaline formate65405-72-3 DFHJK 16 4-methyl-1-oxaspiro[5.5]undecan-4-ol 57094-40-3CFGIJK 17 7-methyl-2H-benzo[b][1,4]dioxepin- 28940-11-6 CGIK 3(4H)-one18 1,8-dioxacycloheptadecan-9-one 1725-01-5 DGJ 214-(tert-pentyl)cyclohexan-1-one 16587-71-6 ADFGIJKL 22 o-Phenyl anisol86-26-0 DEFHJK 23 3a,5,6,7,8,8b-hexahydro- 823178-41-2 DEFHJK2,2,6,6,7,8,8-heptamethyl-4H- indeno(4,5-d)-1,3-dioxole 257-isopropyl-8,8-dimethyl-6,10- 62406-73-9 BDEFHIJK dioxaspiro[4.5]decane28 Octyl 2-furoate 39251-88-2 DEFHJK 29 Octyl acetate 112-14-1 BDEFHJKL30 octanal propylene glycol acetal 74094-61-4 BDEFHJKL 31 Octanal124-13-0 ACHIKL 32 Octanal dimethyl acetal 10022-28-3 ACEFGJKL 33Myrcene 123-35-3 ADEFGIKL 34 Myrcenol 543-39-5 BCEFGIJK 35 Myrcenylacetate 1118-39-4 ADEFGJK 36 Myristaldehyde 124-25-4 DFHJK 37Myristicine 607-91-0 CGJK 38 Myristyl nitrile 629-63-0 DEFHJK 392,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a- 103614-86-4 DEFHIJKoctahydronaphthalen-1-ol 42 Ocimenol 5986-38-9 BCHIJK 43 Ocimenol28977-58-4 BCHIJK 47 Nopyl acetate 128-51-8 DEFHJK 48 Nootkatone4674-50-4 DHJK 49 Nonyl alcohol 143-08-8 BDEFGIJKL 50 Nonaldehyde124-19-6 ADHIKL 52 12-methyl-14-tetradec-9-enolide 223104-61-8 DFHJK 57N-ethyl-p-menthane-3-carboxamide 39711-79-0 DEFGIJK 611-(3-methylbenzofuran-2-yl)ethan-1-one 23911-56-0 CEFHIK 622-methoxynaphthalene 93-04-9 BDEFHK 63 Nerolidol 7212-44-4 DEFHJK 64Nerol 106-25-2 BCHIK 65 1-ethyl-3-methoxytricyclo[2.2.1.02,6]heptane31996-78-8 ACEFHIJKL 67 Methyl (E)-non-2-enoate 111-79-5 ADEFHJKL 6810-isopropyl-2,7-dimethyl-1- 89079-92-5 BDEFHIJKoxaspiro[4.5]deca-3,6-diene 69 2-(2-(4-methylcyclohex-3-en-1- 95962-14-4DHJK yl)propyl)cyclopentan-1-one 70 Myrtenal 564-94-3 ACFHIJKL 71(E)-4-(2,2,3,6- 54992-90-4 BDEFHIJK tetramethylcyclohexyl)but-3-en-2-one74 Myraldyl acetate 53889-39-7 DHJK 75 Musk tibetine 145-39-1 DHIJ 761,7-dioxacycloheptadecan-8-one 3391-83-1 DGJ 77 Musk ketone 81-14-1 DHJ78 Musk ambrette 83-66-9 DHIJ 79 3-methylcyclopentadecan-1-one 541-91-3DEFHJK 80 (E)-3-methylcyclopentadec-4-en-1-one 82356-51-2 DHJK 823-methyl-4-phenylbutan-2-ol 56836-93-2 BCEFHIK 831-(4-isopropylcyclohexyl)ethan-1-ol 63767-86-2 BDEFHIJK 85 Milk Lactone72881-27-7 DEFHJK 91 Methyl octine carbonate 111-80-8 BDEFHKL 92 Methyloctyl acetaldehyde 19009-56-4 ADFHJKL 936,6-dimethoxy-2,5,5-trimethylhex-2-ene 67674-46-8 ACHIJKL 98 Methylphenylethyl carbinol 2344-70-9 BCEFHIK 100 Methyl stearate 112-61-8DEFHJ 101 Methyl nonyl acetaldehyde dimethyl acetal 68141-17-3 BDEFHJK102 Methyl nonyl ketone 112-12-9 BDFHJKL 103 Methyl nonyl acetaldehyde110-41-8 BDFHJK 104 Methyl myristate 124-10-7 DEFHJK 105 Methyllinoleate 112-63-0 DEFHJ 106 Methyl lavender ketone 67633-95-8 CFHJK 108Methyl isoeugenol 93-16-3 ACEFHK 109 Methyl hexadecanoate 112-39-0DEFHJK 110 Methyl eugenol 93-15-2 ACEFHK 112 Methyl epijasmonate1211-29-6 CHJK 113 Methyl dihydrojasmonate 24851-98-7 DFHJK 114 Methyldiphenyl ether 3586-14-9 DEFHJK 117 Methyl cinnamate 103-26-4 BCEFHK 119Methyl chavicol 140-67-0 ADEFHK 120 Methyl beta-naphthyl ketone 93-08-3CEFHK 122 Methyl 2-octynoate 111-12-6 ACEFHKL 123 Methylalpha-cyclogeranate 28043-10-9 ACHIJKL 126 Methoxycitronellal 3613-30-7ACFGIJK 128 Menthone 1,2-glycerol ketal 67785-70-0 CEFHJ (racemic) 130Octahydro-1H-4,7-methanoindene-1- 30772-79-3 BCFHIJKL carbaldehyde 1343-(3-(tert-butyl)phenyl)-2- 62518-65-4 BDHJK methylpropanal 135(E)-4-(4,8-dimethylnona-3,7-dien-1- 38462-23-6 DEFHJK yl)pyridine 137(E)-trideca-3,12-dienenitrile 134769-33-8 DEFHJK 1402,2-dimethyl-3-(m-tolyl)propan-1-ol 103694-68-4 CEFHIJK 1412,4-dimethyl-4,4a,5,9b- 27606-09-3 CEFHJKtetrahydroindeno[1,2-d][1,3]dioxine 142 Maceal 67845-30-1 BDFHJK 1434-(4-hydroxy-4- 31906-04-4 CHJ methylpentyl)cyclohex-3-ene-1-carbaldehyde 145 1-Limonene 5989-54-8 ADEFGIJKL 146(Z)-3-hexen-1-yl-2-cyclopenten-1-one 53253-09-1 BDHK 148 Linalyloctanoate 10024-64-3 DEFHJ 149 Linalyl isobutyrate 78-35-3 BDHJK 152Linalyl benzoate 126-64-7 DFHJ 153 Linalyl anthranilate 7149-26-0 DFHJ155 Linalool oxide (furanoid) 60047-17-8 BCHIJK 156 linalool oxide1365-19-1 CGIJK 158 (2Z,6E)-3,7-dimethylnona-2,6- 61792-11-8 BDEFHJKdienenitrile 159 3-(4-methylcyclohex-3-en-1- 6784-13-0 ACFHIJKyl)butanal 161 (2,5-dimethyl-1,3-dihydroinden-2- 285977-85-7 CEFHJKyl)methanol 162 3-(4-(tert-butyl)phenyl)-2- 80-54-6 BDHJK methylpropanal167 (E)-1-(1-methoxypropoxy)hex-3-ene 97358-54-8 ACEFGJKL 168 Leafacetal 88683-94-7 ACEFGJKL 170 1-Carveol 2102-58-1 BCHIJK 174 Laurylalcohol 112-53-8 DEFGJK 175 Lauryl acetate 112-66-3 DEFHJK 176 Lauricacid 143-07-7 DEFHJ 177 Lactojasmone 7011-83-8 BDEFHIJKL 178Lauraldehyde 112-54-9 BDFHJK 1793,6-dimethylhexahydrobenzofuran-2(3H)-one 92015-65-1 BCEFHIJKL 1824-(1-ethoxyvinyl)-3,3,5,5- 36306-87-3 BDFHIJKtetramethylcyclohexan-1-one 183 Khusimol 16223-63-5 CEFHJK 1845-(sec-butyl)-2-(2,4- 117933-89-8 DEFHJ dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane 185 (1-methyl-2-((1,2,2- 198404-98-7 DEFHJKtrimethylbicyclo[3.1.0]hexan-3- yl)methyl)cyclopropyl)methanol 1862-propylheptanenitrile 208041-98-9 ADEFHIJKL 187(E)-6-(pent-3-en-1-yl)tetrahydro-2H- 32764-98-0 BCFHIKL pyran-2-one 1892-hexylcyclopentan-1-one 13074-65-2 BDFHJKL 1902-methyl-4-phenyl-1,3-dioxolane 33941-99-0 BCEFGIK 1922,6,9,10-tetramethyl-1- 71078-31-4 BDEFHIJK oxaspiro(4.5)deca-3,6-diene193 Isopulegol 89-79-2 BCEFHIJKL 195 Isopropyl palmitate 142-91-6 DEFHJ196 Isopropyl myristate 110-27-0 DEFHJK 197 Isopropyl dodecanoate10233-13-3 DEFHJK 199 Isopimpinellin 482-27-9 CFGJ 206Iso3-methylcyclopentadecan-1-one 3100-36-5 DEFGJK 208 Isomenthone491-07-6 ADEFGIJKL 209 Isojasmone 95-41-0 BDFHJKL 210 Isomenthone36977-92-1 ADEFGIJKL 211 Isohexenyl cyclohexenyl 37677-14-8 DFHJKcarboxaldehyde 212 Isoeugenyl benzyl ether 120-11-6 DFHJ 2151-((2S,3S)-2,3,8,8-tetramethyl- 54464-57-2 DHJK1,2,3,4,5,6,7,8-octahydronaphthalen- 2-yl)ethan-1-one 218 Isocyclocitral1335-66-6 ACFHIJKL 221 Isobutyl quinoline 65442-31-1 DEFHJK 227Isobornylcyclohexanol 68877-29-2 DEFHJK 228 Isobornyl propionate2756-56-1 BDEFHIJK 229 Isobornyl isobutyrate 85586-67-0 BDEFHIJK 230Isobornyl cyclohexanol 66072-32-0 DEFHJK 231 Isobornyl acetate 125-12-2ADEFHIJKL 233 Isobergamate 68683-20-5 DEFHJK 234 Isoamyl undecylenate12262-03-2 DEFHJK 238 Isoamyl laurate 6309-51-9 DEFHJK 242Isoambrettolide 28645-51-4 DGJ 243 Irisnitrile 29127-83-1 ADEFHKL 244Indolene 68527-79-7 DEFHJ 246 Indol/Hydroxycitronellal Schiff base67801-36-9 DEFHJ 247 4,4a,5,9b-tetrahydroindeno[1,2- 18096-62-3 BCEFGJKd][1,3]dioxine 249 Hydroxy-citronellol 107-74-4 CEFGIJK 2522-cyclododecylpropan-1-ol 118562-73-5 DEFHJK 253 Hydrocitronitrile54089-83-7 CEFHJK 254 Hydrocinnamyl alcohol 122-97-4 BCEFHIK 256Hydratropaldehyde dimethyl acetal 90-87-9 ACEFHJK 2595-ethyl-4-hydroxy-2-methylfuran- 27538-09-6 CFGIK 3(2H)-one 2602,3-dihydro-3,3-dimethyl-1H-indene- 173445-44-8 DHJK 5-propanal 2613-(3,3-dimethyl-2,3-dihydro-1H- 173445-65-3 DHJK inden-5-yl)propanal 263Hexyl octanoate 1117-55-1 DEFHJK 267 Hexyl hexanoate 6378-65-0 DEFHJKL269 Hexyl cinnamic aldehyde 101-86-0 DHJ 271 Hexyl benzoate 6789-88-4DEFHJK 274 Hexenyl tiglate 84060-80-0 BDEFHJK 276(E)-3,7-dimethylocta-2,6-dien-1-yl 3681-73-0 DEFHJ palmitate 277Hexadecanolide 109-29-5 DEFGJK 278 2-butyl-4,4,6-trimethyl-1,3-dioxane54546-26-8 ADEFHIJKL 280 Ethyl (1R,2R,3R,4R)-3- 116126-82-0 BDEFHIJKisopropylbicyclo[2.2.1]hept-5-ene-2- carboxylate 2813a,4,5,6,7,7a-hexahydro-1H-4,7- 5413-60-5 CEFGJK methanoinden-6-ylacetate 285 2-(1-(3,3- 141773-73-1 DEFHJ dimethylcyclohexyl)ethoxy)-2-methylpropyl propionate 286 Heliotropine diethyl acetal 40527-42-2 CEFGJ288 Helional 1205-17-0 CHJK 289 (E)-oxacyclohexadec-13-en-2-one111879-80-2 DGJK 290 Gyrane 24237-00-1 ADEFHIJKL 292 Guaiol 489-86-1DEFHJK 293 1-(2,6,6-trimethylcyclohex-2-en-1- 68611-23-4 DHJKyl)pentan-3-one 294 Ethyl 2-ethyl-6,6-dimethylcyclohex- 57934-97-1BDEFHIJK 2-ene-1-carboxylate 295 Germacrene B 15423-57-1 DEFHJK 296Germacrene D 23986-74-5 DEFHJK 300 Geranyl phenylacetate 102-22-7 DFHJ301 Geranyl phenyl acetate 71648-43-6 DFHJ 303 Geranyl linalool1113-21-9 DFHJ 307 Geranyl cyclopentanone 68133-79-9 DHJK 316gamma-Undecalactone (racemic) 104-67-6 DEFHJKL 317 gamma-Terpinylacetate 10235-63-9 BDHJK 318 gamma-Terpineol 586-81-2 BCGIJK 321gamma-Nonalactone 104-61-0 BCEFHIKL 322 gamma-Muurolene 30021-74-0DEFHJKL 323 gamma-(E)-6-(pent-3-en-1- 63095-33-0 BCEFHKLyl)tetrahydro-2H-pyran-2-one 324 gamma-Ionone 79-76-5 BDEFHIJK 325gamma-Himachalene 53111-25-4 BDEFHJKL 328 gamma-Gurjunene 22567-17-5DEFHJKL 329 gamma-Eudesmol 1209-71-8 DFHJK 330 gamma-Dodecalactone2305-05-7 DEFHJK 331 gamma-Damascone 35087-49-1 BDEFHIJK 332gamma-Decalactone 706-14-9 BDEFHIJKL 333 gamma-Cadinene 39029-41-9DEFHJKL 334 1-(3,3-dimethylcyclohexyl)pent-4- 56973-87-6 BDEFHJKen-1-one 335 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8- 1222-05-5 DEFHJKhexahydrocyclopenta[g]isochromene 336 Furfuryl octanoate 39252-03-4DEFHJK 338 Furfuryl hexanoate 39252-02-3 CEFHJK 339 Furfuryl heptanoate39481-28-2 CEFHJK 342 2-methyldecanenitrile 69300-15-8 BDEFHJKL 3438,8-dimethyl-3a,4,5,6,7,7a- 76842-49-4 DEFHJKhexahydro-1H-4,7-methanoinden-6- yl propionate 344 Ethyl(3aR,4S,7R,7aR)-octahydro- 80657-64-3 DEFHIJK 3aH-4,7-methanoindene-3a-carboxylate 347 Diethyl cyclohexane-1,4- 72903-27-6 CEFHJK dicarboxylate349 (6-isopropyl-9-methyl-1,4- 63187-91-7 CEFHJdioxaspiro[4.5]decan-2-yl)methanol 350 2-isobutyl-4-methyltetrahydro-2H-63500-71-0 BCEFHIJK pyran-4-ol 352 Undec-10-enenitrile 53179-04-7BDEFHJK 353 (Z)-6-ethylideneoctahydro-2H-5,8- 69486-14-2 CEFGJKmethanochromen-2-one 356 3-(2-ethylphenyl)-2,2- 67634-15-5 BDHJKdimethylpropanal 358 (E)-4,8-dimethyldeca-4,9-dienal 71077-31-1 BDFHJK359 (E)-4-((3aR,4R,7R,7aR)- 501929-47-1 DEFHJK1,3a,4,6,7,7a-hexahydro-5H-4,7- methanoinden-5-ylidene)-3-methylbutan-2-ol 360 8,8-dimethyl-3a,4,5,6,7,7a- 171102-41-3 DEFHJKhexahydro-1H-4,7-methanoinden-6- yl acetate 361 3-(4-ethylphenyl)-2,2-134123-93-6 DEFHJK dimethylpropanenitrile 362 2-heptylcyclopentan-1-one137-03-1 DFHJKL 363 1-ethoxyethoxy Cyclododecane 389083-83-4 DEFHJK 3643-cyclohexene-1-carboxylic acid, 815580-59-7 ACHIJKL 2,6,6-trimethyl-,methyl ester 368 Farnesyl acetate 29548-30-9 DEFHJK 369 Farnesol4602-84-0 DEFHJK 370 Oxacyclohexadecan-2-one 106-02-5 DEFGJK 3711-cyclopentadec-4-en-1-one 14595-54-1 DEFGJK 3721-cyclopentadec-4-en-1-one 35720-57-1 DEFGJK 373 2-methoxy-4-(4-128489-04-3 CGJ methylenetetrahydro-2H-pyran-2-yl)phenol 374 Eugenylacetate 93-28-7 CFHJK 375 Eugenol 97-53-0 CHIK 377Ethylmethylphenylglycidate 77-83-8 CFHJK 378 Ethylene brassylate105-95-3 DFGJ 381 Ethyl undecylenate 692-86-4 DEFHJK 385 Ethyl palmitate628-97-7 DEFHJ 386 Ethyl nonanoate 123-29-5 BDEFHJKL 388 Ethyl myristate124-06-1 DEFHJK 390 Ethyl linalool 10339-55-6 BCEFHJK 391 Ethyl laurate106-33-2 DEFHJK 394 Ethyl hexyl ketone 925-78-0 ADFHIKL 397 Ethyldecanoate 110-38-3 BDEFHJK 398 Ethyl gamma-Safranate 35044-57-6 ADHIJK407 Ethyl 3-phenylglycidate 121-39-1 CGJK 4136-ethyl-2,10,10-trimethyl-1- 79893-63-3 BDEFHIJKoxaspiro[4.5]deca-3,6-diene 414 Elemol 639-99-6 DEFHJK 415(2-(1-ethoxyethoxy)ethyl)benzene 2556-10-7 BCEFHJK 416(E)-3-methyl-5-(2,2,3- 67801-20-1 DHJKtrimethylcyclopent-3-en-1-yl)pent-4-en-2-ol 417 d-xylose 58-86-6 CGIJ418 (E)-4-((3aS,7aS)-octahydro-5H-4,7- 30168-23-1 DFHJKmethanoinden-5-ylidene)butanal 421 Dodecanal dimethyl acetal 14620-52-1DEFHJK 424 d-Limonene 5989-27-5 ADEFGIJKL 425 Dipropylene Glycol25265-71-8 CEFGIK 426 Dispirone 83863-64-3 BDEFHJK 428 Diphenyloxide101-84-8 BDEFHK 429 Diphenylmethane 101-81-5 DEFGK 432 Dimethyl benzylcarbinyl butyrate 10094-34-5 DEFHJK 436 2,6-dimethyloct-7-en-4-one1879-00-1 ADEFHIJKL 441 Octahydro-1H-4,7-methanoinden-5- 64001-15-6DEFHJKL yl acetate 444 Dihydrocarveol acetate 20777-49-5 BDEFHIJK 445Dihydrocarveol 619-01-2 BCEFHIJKL 449 Dihydro Linalool 18479-51-1BCEFGIJKL 450 Dihydro Isojasmonate 37172-53-5 DHJK 453 Dibutyl sulfide544-40-1 ADEFHIKL 457 Dibenzyl 103-29-7 DEFGJK 459 delta-Undecalactone710-04-3 DEFHJKL 461 delta-Elemene 20307-84-0 BDEFHJK 462 delta-Guaiene3691-11-0 DEFHJKL 463 delta-Dodecalactone 713-95-1 DEFHJK 464delta-Decalactone 705-86-2 BDEFHIJKL 465 delta-Cadinene 483-76-1 DEFHJKL466 delta-damascone 57378-68-4 ADHIJK 467 delta-Amorphene 189165-79-5DEFHJKL 468 delta-3-Carene 13466-78-9 ADEFGIJKL 470 Decylenic alcohol13019-22-2 BDEFHJK 471 Decyl propionate 5454-19-3 DEFHJK 473 Decanaldiethyl acetal 34764-02-8 DEFHJK 474 Decahydro-beta-naphthol 825-51-4BCEFGIK 475 1-cyclohexylethyl (E)-but-2-enoate 68039-69-0 BDFHJK 4783-(4-isopropylphenyl)-2- 103-95-7 BDFHJK methylpropanal 479Cyclotetradecane 295-17-0 DEFGJKL 480 Cyclopentadecanone 502-72-7 DEFGJK482 Cyclohexyl salicylate 25485-88-5 DFGJ 4843a,4,5,6,7,7a-hexahydro-1H-4,7- 113889-23-9 DEFHJK methanoinden-6-ylbutyrate 485 Cyclic ethylene dodecanedioate 54982-83-1 DFGJ 4868,8-dimethyl-1,2,3,4,5,6,7,8- 68991-97-9 DHJKoctahydronaphthalene-2-carbaldehyde 487 3a,4,5,6,7,7a-hexahydro-1H-4,7-67634-20-2 DEFHJK methanoinden-5-yl isobutyrate 488 Curzerene 17910-09-7DHJK 491 Cumic alcohol 536-60-7 CHIJK 493 Coumarone 1646-26-0 BCEFHIK497 2-(3-phenylpropyl)pyridine 2110-18-1 CEFHJK 498 Dodecanenitrile2437-25-4 DEFHJK 501 (E)-cycloheptadec-9-en-1-one 542-46-1 DEFGJ 502Citryl acetate 6819-19-8 DFHJK 503 Citrus Propanol 15760-18-6 CEFHIJK505 Citronitrile 93893-89-1 CEFHJK 519 Citral propylene glycol acetal10444-50-5 CEFHJK 520 Citral dimethyl acetal 7549-37-3 BCEFHJK 521Citral diethyl acetal 7492-66-2 BDEFHJK 524 cis-Ocimene 3338-55-4 ADGIKL527 cis-Limonene oxide 13837-75-7 ADEFGIJKL 529 Cis-iso-ambrettolide36508-31-3 DGJ 530 cis-6-nonenol 35854-86-5 BCEFHIKL 531 cis-carveol1197-06-4 BCHIJK 532 cis-4-Decen-1-al 21662-09-9 ADHKL 534cis-3-hexenyl-cis-3-hexenoate 61444-38-0 BDEFHJK 537 cis-3-Hexenylsalicylate 65405-77-8 DEFGJ 541 Cis-3-hexenyl Benzoate 25152-85-6 DEFHJK544 cis-3-Hexenyl 2-methylbutyrate 53398-85-9 ADEFHJKL 546 cis-3,cis-6-nonadienol 53046-97-2 ACEFHK 548 Cinnamyl propionate 103-56-0DEFHJK 550 Cinnamyl isobutyrate 103-59-3 DEFHJK 551 Cinnamyl formate104-65-4 BCEFHK 552 Cinnamyl cinnamate 122-69-0 DHJ 553 Cinnamyl acetate103-54-8 BCEFHK 555 Cinnamic alcohol 104-54-1 BCEFHIK 558 Cetyl alcohol36653-82-4 DEFHJ 559 (E)-1-(2,6,6-trimethylcyclohex-2-en- 79-78-7 DHJK1-yl)hepta-1,6-dien-3-one 560 2-methyl-4-(2,6,6-trimethylcyclohex-65405-84-7 DFHJK 1-en-1-yl)butanal 561 (3aR,5aR,9aR,9bR)-3a,6,6,9a-3738-00-9 DEFHJK tetramethyldodecahydronaphtho[2,1- b]furan 5621,6-dioxacycloheptadecan-7-one 6707-60-4 DGJ 5631-(6-(tert-butyl)-1,1-dimethyl-2,3- 13171-00-1 DEFHJKdihydro-1H-inden-4-yl)ethan-1-one 565 Cedryl methyl ether 19870-74-7ADEFHJK 566 Cedryl formate 39900-38-4 BDEFHJK 567 Cedryl acetate 77-54-3DEFHJK 568 (4Z,8Z)-1,5,9-trimethyl-13- 71735-79-0 DFHJKoxabicyclo[10.1.0]trideca-4,8-diene 569 Cedrol 77-53-2 DEFHJK 5705-methyl-1-(2,2,3- 139539-66-5 DEFHJK trimethylcyclopent-3-en-1-yl)-6-oxabicyclo[3.2.1]octane 571 5-methyl-1-(2,2,3- 426218-78-2 DFHJtrimethylcyclopent-3-en-1-yl)-6- oxabicyclo[3.2.1]octane 5721,1,2,3,3-pentamethyl-1,2,3,5,6,7- 33704-61-9 BDEFHIJKhexahydro-4H-inden-4-one 573 Caryophyllene alcohol acetate 32214-91-8DEFHJK 574 Caryolan-1-ol 472-97-9 DEFHJK 577 Carvyl acetate 97-42-7BDHIJK 578 Caprylnitrile 124-12-9 ACEFGIKL 580 Caprylic alcohol 111-87-5ACEFGIKL 581 Caprylic acid 124-07-2 BCEFHIK 582 Capric acid 334-48-5DEFHJK 584 Capraldehyde 112-31-2 ADHKL 586 3-(4-methoxyphenyl)-2-5462-06-6 BCHJK methylpropanal 587 Camphorquinone 10373-78-1 ACEFGIJK589 Camphene 79-92-5 ADEFGIJKL 591 Ethyl 2-methyl-4-oxo-6- 59151-19-8DHJ pentylcyclohex-2-ene-1-carboxylate 592 Butylated hydroxytoluene128-37-0 DEFGIJK 594 Butyl stearate 123-95-5 DEFHJ 595 Butyl butyryllactate 7492-70-8 CEFGJK 599 Butyl 10-undecenoate 109-42-2 DEFHJK 6002-methyl-4-(2,2,3- 72089-08-8 DEFHJKtrimethylcyclopent-3-en-1-yl)butan-1-ol 6013-(4-(tert-butyl)phenyl)propanal 18127-01-0 BDHJK 603 Bornyl isobutyrate24717-86-0 BDEFHIJK 604 Bornyl acetate 76-49-3 ADEFHIJKL 6062-ethoxy-2,6,6-trimethyl-9- 68845-00-1 BDEFHJKmethylenebicyclo[3.3.1]nonane 607 (ethoxymethoxy)cyclododecane58567-11-6 DEFHJK 608 Bisabolene 495-62-5 DEFHJK 609 Bigarade oxide72429-08-4 ADEFHJKL 610 beta-Vetivone 18444-79-6 DHJK 611 beta-Terpinylacetate 10198-23-9 BDHJK 612 beta-Terpineol 138-87-4 BCGIJK 613beta-Sinensal 60066-88-8 DHJK 614 beta-Sesquiphellandrene 20307-83-9DEFHJK 615 beta-Selinene 17066-67-0 BDEFGJK 616 beta-Santalol 77-42-9DEFHJK 618 beta-Pinene 127-91-3 ADEFGIJKL 620 beta-Naphthyl ethyl ether93-18-5 BDEFHJK 621 beta-Patchoulline 514-51-2 BDEFGJKL 624beta-Himachalene Oxide 57819-73-5 BDFHJK 625 beta-Himachalene 1461-03-6DEFHJKL 626 beta-Guaiene 88-84-6 DEFHJKL 627 (2,2-dimethoxyethyl)benzene101-48-4 DHJK 628 beta-Farnesene 18794-84-8 DEFHJK 631 beta-Copaene18252-44-3 BDEFHJKL 632 beta-Cedrene 546-28-1 BDEFGJKL 633beta-Caryophyllene 87-44-5 DEFHJKL 635 beta-Bisabolol 15352-77-9 DFHJK636 Beta ionone epoxide 23267-57-4 BDEFHIJK 638 Bergaptene 484-20-8 CGJ639 Benzyl-tert-butanol 103-05-9 CEFGJK 644 Benzyl laurate 140-25-0DEFHJ 649 Benzyl dimethyl carbinol 100-86-7 BCEFGIK 650 Benzyl cinnamate103-41-3 DHJ 653 Benzyl benzoate 120-51-4 DHJ 655 Benzophenone 119-61-9DEFHK 658 7-isopentyl-2H- 362467-67-2 DHJbenzo[b][1,4]dioxepin-3(4H)-one 659 2′-isopropyl-1,7,7- 188199-50-0DEFHJK trimethylspiro[bicyclo[2.2.1]heptane- 2,4′-[1,3]dioxane] 6604-(4-methylpent-3-en-1-yl)cyclohex- 21690-43-7 DEFHJK3-ene-1-carbonitrile 661 Aurantiol 89-43-0 DEFHJ 663 Anisylphenylacetate 102-17-0 DFHJ 668 Methyl (E)-octa-4,7-dienoate 189440-77-5ACEFHKL 671 Amyl Cinnamate 3487-99-8 DEFHJK 673(3aR,5aS,9aS,9bR)-3a,6,6,9a- 6790-58-5 DEFHJKtetramethyldodecahydronaphtho[2,1- b]furan 674(4aR,5R,7aS,9R)-2,2,5,8,8,9a- 211299-54-6 DEFHJKhexamethyloctahydro-4H-4a,9- methanoazuleno[5,6-d][1,3]dioxole 6752,5,5-trimethyl-1,2,3,4,5,6,7,8- 71832-76-3 DEFHJKoctahydronaphthalen-2-ol 676 2,5,5-trimethyl-1,2,3,4,5,6,7,8- 41199-19-3DEFHJK octahydronaphthalen-2-ol 677 1-((2-(tert- 139504-68-0 DEFHJKbutyl)cyclohexyl)oxy)butan-2-ol 678 (3S,5aR,7aS,11aS,11bR)-3,8,8,11a-57345-19-4 DEFHJ tetramethyldodecahydro-5H-3,5a-epoxynaphtho[2,1-c]oxepine 679 2,2,6,6,7,8,8-heptamethyldecahydro-476332-65-7 ADEFHJK 2H-indeno[4,5-b]furan 6802,2,6,6,7,8,8-heptamethyldecahydro- 647828-16-8 ADEFHJK2H-indeno[4,5-b]furan 681 Amber acetate 37172-02-4 BDEFHJK 682Alpinofix ® 811436-82-5 DEFHJ 683 alpha-Thujone 546-80-5 ADEFGIJKL 684alpha-Vetivone 15764-04-2 DHJK 686 alpha-Terpinyl propionate 80-27-3BDEFHJK 691 alpha-Sinensal 17909-77-2 DHJK 692 alpha-Selinene 473-13-2BDEFHJK 693 alpha-Santalene 512-61-8 ADEFHJKL 694 alpha-Santalol115-71-9 DEFHJK 696 alpha-Patchoulene 560-32-7 ADEFHJKL 697alpha-neobutenone 56973-85-4 BDHJK 698 alpha-Muurolene 10208-80-7DEFHJKL 700 alpha-methyl ionone 127-42-4 BDHJK 702 alpha-Limonene138-86-3 ADEFGIJKL 704 alpha-Irone 79-69-6 BDHJK 706 alpha-Humulene6753-98-6 DEFHJK 707 alpha-Himachalene 186538-22-7 BDEFHJK 708alpha-Gurjunene 489-40-7 BDEFHJKL 709 alpha-Guaiene 3691-12-1 DEFHJKL710 alpha-Farnesene 502-61-4 DEFHJK 711 alpha-Fenchene 471-84-1ADEFGIJKL 712 alpha-Eudesmol 473-16-5 DEFHJK 713 alpha-Curcumene4176-17-4 DEFHJK 714 alpha-Cubebene 17699-14-8 ADEFHJKL 715alpha-Cedrene epoxide 13567-39-0 ADEFHJK 716 alpha-Cadinol 481-34-5DEFHJK 717 alpha-Cadinene 24406-05-1 DEFHJKL 718 alpha-Bisabolol515-69-5 DFHJK 719 alpha-bisabolene 17627-44-0 DEFHJK 720alpha-Bergamotene 17699-05-7 BDEFHJKL 721 alpha-Amylcinnamyl alcohol101-85-9 DEFHJ 722 alpha-Amylcinnamyl acetate 7493-78-9 DEFHJ 723alpha-Amylcinnamaldehyde diethyl 60763-41-9 DEFHJ acetal 724alpha-Amylcinnamaldehyde 122-40-7 DHJK 725 alpha-Amorphene 23515-88-0DEFHJKL 726 alpha-Agarofuran 5956-12-7 BDEFHJK 7271-methyl-4-(4-methyl-3-penten-1- 52475-86-2 DFHJKyl)-3-Cyclohexene-1-carboxaldehyde 730 1-Phenyl-2-pentanol 705-73-7CEFHK 731 1-Phenyl-3-methyl-3-pentanol 10415-87-9 CEFHJK 7332,3,4-trimethoxy-benzaldehyde 2103-57-3 BCGI 7352,4,5-trimethoxy-benzaldehyde 4460-86-0 BCG 7362,4,6-trimethoxybenzaldehyde 830-79-5 BCGI 738 2,4-Nonadienal 6750-03-4ACHKL 741 2,6,10-Trimethylundecanal 105-88-4 BDFGJK 742 alpha,4-Dimethylbenzenepropanal 41496-43-9 ACHJK 746 Allyl cyclohexyl propionate2705-87-5 BDEFHJK 748 Allyl amyl glycolate 67634-00-8 BCEFGJK 750Allo-aromadendrene 25246-27-9 BDEFHJKL 752 Aldehyde C-11 143-14-6 ADHJK754 Methyl (E)-2-(((3,5- 94022-83-0 DEFHJ dimethylcyclohex-3-en-1-yl)methylene)amino)benzoate 757 2,6,10-trimethylundec-9-enal 141-13-9BDFHJK 758 Acetoxymethyl-isolongifolene 59056-62-1 BDEFHJK (isomers) 763Acetate C9 143-13-5 BDEFHJKL 764 Acetarolle ® 744266-61-3 DFHJK 766Acetaldehyde phenylethyl propyl 7493-57-4 CEFHJK acetal 767 Acetaldehydedipropyl acetal 105-82-8 ACEFGIKL 768 Acetaldehyde benzyl 2-methoxyethyl7492-39-9 BCEFHJK acetal 769 (Z)-2-(4-methylbenzylidene)heptanal84697-09-6 DHJ 770 9-decenal 39770-05-3 ADHKL 771 8-Hexadecenolide123-69-3 DGJ 772 7-Methoxycoumarin 531-59-9 CHK 774 7-epi-alpha-Selinene123123-37-5 BDEFHJK 775 7-eip-alpha-Eudesmol 123123-38-6 DEFHJK 7767-Acetyl-1,1,3,4,4,6- 1506-02-1 DEFHJ hexamethyltetralin 7786-Isopropylquinoline 135-79-5 CEFHJK 781 6,6-dimethyl-2-norpinene-2-33885-51-7 BCFHJK propionaldehyde 782 6,10,14-trimethyl-2-Pentadecanone502-69-2 DEFHJK 786 5-Isopropenyl-2-methyl-2- 13679-86-2 ACGIJKLvinyltetrahydrofuran 788 5-Cyclohexadecenone 37609-25-9 DEFGJK 7914-Terpinenol 562-74-3 BCHIJK 792 4-Pentenophenone 3240-29-7 BCEFHIK 8004-Carvomenthenol 28219-82-1 BCHIJK 802 4,5,6,7-Tetrahydro-3,6- 494-90-6BCEFHIJKL dimethylbenzofuran 803 4-(p-Methoxyphenyl)-2-butanone 104-20-1BCEFHJK 804 3-Thujopsanone 25966-79-4 BDEFHJK 805 3-Propylidenephthalide17369-59-4 CEFHK 806 3-Nonylacrolein 20407-84-5 BDFHJK 8073-Methyl-5-phenyl-1-pentanal 55066-49-4 BDFHJK 814 3-Hexenyl isovalerate10032-11-8 ADEFHJKL 821 3,6-Dimethyl-3-octanyl acetate 60763-42-0ADEFHIJKL 824 3,4,5-trimethoxybenzaldehyde 86-81-7 BCGIK 826 3-(p-7775-00-0 BDFHJK Isopropylphenyl)propionaldehyde 827 2-Undecenenitrile22629-48-7 BDEFHJK 828 2-Undecenal 2463-77-6 ADHJK 8292-trans-6-trans-Nonadienal 17587-33-6 ACHKL 831 2-Phenylethyl butyrate103-52-6 DEFHJK 833 2-Phenyl-3-(2-furyl)prop-2-enal 57568-60-2 CHJ 8342-Phenoxyethanol 122-99-6 BCEFGIK 837 2-Nonen-1-al 2463-53-8 ADHKL 8392-Nonanol 628-99-9 BDEFGIKL 840 2-Nonanone 821-55-6 ADFHIKL 8492-Isobutyl quinoline 93-19-6 CEFHJK 850 2-Hexylidene cyclopentanone17373-89-6 DFHJKL 852 2-Heptyl tetrahydrofuran 2435-16-7 BDEFHJKL 8562-Decenal 3913-71-1 ADHKL 864 2,6-Nonadienal 26370-28-5 ACHKL 8652,6-Nonadien-1-ol 7786-44-9 ACEFHK 866 2,6-dimethyl-octanal 7779-07-9ADFGIJKL 868 1-Decanol 112-30-1 BDEFGJK 869 1-Hepten-1-ol, 1-acetate35468-97-4 ACEFHKL 870 10-Undecen-1-ol 112-43-6 DEFHJK 871 10-Undecenal112-45-8 ADHJK 872 10-epi-gamma-Eudesmol 15051-81-7 DFHJK 8731,8-Thiocineol 68391-28-6 ADEFHIJKL 876 1,3,5-undecatriene 16356-11-9ADEFHJKL 877 1,2-Dihydrolinalool 2270-57-7 BCEFGIJKL 8781,3,3-trimethyl-2-norbornanyl 13851-11-1 ADEFHIJKL acetate 8791,1,2,3,3-Pentamethylindan 1203-17-4 ADHIJKL 881(Z)-6,10-dimethylundeca-5,9-dien-2- 3239-37-0 DEFHJK yl acetate 884(Z)-3-Dodecenal 68141-15-1 BCFHJK 885 (S)-gamma-Undecalactone 74568-05-1DEFHJKL 886 (R)-gamma-Undecalactone 74568-06-2 DEFHJKL 890(E)-6,10-dimethylundeca-5,9-dien-2- 3239-35-8 DEFHJK yl acetat 892(2Z)-3-methyl-5-phenyl-2- 53243-59-7 DEFHJK Pentenenitrile 893(2S,5S,6S)-2,6,10,10-tetramethyl-1- 65620-50-0 DFHIJKoxaspiro[4_5]decan-6-ol 894 (2E)-3-methyl-5-phenyl-2- 53243-60-0 CEFHJKpentenenitrile 897 (+)-Dihydrocarveol 22567-21-1 BCEFHIJKL 905 Menthone89-80-5 ADEFGIJKL 908 (R,E)-2-methyl-4-(2,2,3- 185068-69-3 CHJKtrimethylcyclopent-3-en-1-yl)but-2- en-1-ol 912 2-(8-isopropyl-6-68901-32-6 DEFHJK methylbicyclo[2.2.2]oct-5-en-2-yl)- 1,3-dioxolane 913gamma-methyl ionone 7388-22-9 BDHIJK 914 3-(3-isopropylphenyl)butanal125109-85-5 BDHJK 916 3-(1-ethoxyethoxy)-3,7- 40910-49-4 BDEFHJKdimethylocta-1,6-diene 919 3a,4,5,6,7,7a-hexahydro-1H-4,7- 17511-60-3CEFHJK methanoinden-6-yl propionate 920 Bulnesol 22451-73-6 DEFHJK 922Benzyl phenylacetate 102-16-9 DHJ 923 Benzoin 119-53-9 CEFHJ 924(E)-1,2,4-trimethoxy-5-(prop-1-en-1- 2883-98-9 BCFGJK yl)benzene 925alpha,alpha,6,6-tetramethyl 33885-52-8 BDFHJKbicyclo[3.1.1]hept-2-ene-propanal 926 7-epi-sesquithujene 159407-35-9DEFHJKL 927 5-Acetyl-1,1,2,3,3,6- 15323-35-0 DEFHJK hexamethylindan 9283-Methylphenethyl alcohol 1875-89-4 BCEFHIK 929 3,6-Nonadien-1-ol76649-25-7 ACEFHK 930 2-Tridecenal 7774-82-5 BDFHJK 933 Patchoulialcohol 5986-55-0 DEFHIJK 937 p-Cresyl isobutyrate 103-93-5 BDHJK 939p-Cresyl n-hexanoate 68141-11-7 DEFHJK 941 5-hexyl-4-methyldihydrofuran-67663-01-8 BDEFHIJKL 2(3H)-one 942 Ethyl (2Z,4E)-deca-2,4-dienoate3025-30-7 BDEFHJK 943 Pelargene 68039-40-7 DEFHJK 9452-cyclohexylidene-2- 10461-98-0 DFHJK phenylacetonitrile 946Perillaldehyde 2111-75-3 ACHIJK 947 Perillyl acetate 15111-96-3 DFHJK948 Perillyl alcohol 536-59-4 CHIJK 950 (2-isopropoxyethyl)benzene68039-47-4 ACEFHJKL 951 Ethyl (2Z,4E)-deca-2,4-dienoate 313973-37-4BDEFHJK 953 (2-(cyclohexyloxy)ethyl)benzene 80858-47-5 DEFHJK 954Phenethyl 2-methylbutyrate 24817-51-4 DEFHJK 955 Phenethyl alcohol60-12-8 BCEFGIK 959 Phenethyl phenylacetate 102-20-5 DHJ 962 Phenoxanol55066-48-3 DEFHJK 965 Phenyl benzoate 93-99-2 DFHJK 967 Phenyl ethylbenzoate 94-47-3 DHJ 969 Phenylacetaldehyde ethyleneglycol 101-49-5BCEFGIK acetal 973 2-(6,6-dimethylbicyclo[3.1.1]hept-2- 30897-75-7ACFHIJKL en-2-yl)acetaldehyde 974 Pinocarveol 5947-36-4 BCEFGIJKL 976Piperonyl acetone 55418-52-5 CEFGJ 978 3a,4,5,6,7,7a-hexahydro-1H-4,7-68039-44-1 DEFHJK methanoinden-6-yl pivalate 980(4aR,8aS)-7-methyloctahydro-1,4- 41724-19-0 CEFGJKLmethanonaphthalen-6(2H)-one 982 p-Menth-3-en-1-ol 586-82-3 BCGIJK 985(E)-3,3-dimethyl-5-(2,2,3- 107898-54-4 DHJKtrimethylcyclopent-3-en-1-yl)pent-4- en-2-ol 9881-methyl-4-(4-methylpent-3-en-1- 52474-60-9 DFHJKyl)cyclohex-3-ene-1-carbaldehyde 993 Propylene glycol 57-55-6 ACEFGIKL998 p-Tolyl phenylacetate 101-94-0 DFHJ 1000 Ethyl 2,4,7-decatrienoate78417-28-4 BDEFHJK 1003 2-benzyl-4,4,6-trimethyl-1,3-dioxane 67633-94-7DEFHJK 1006 2,4-dimethyl-4- 82461-14-1 BDEFHJK phenyltetrahydrofuran1007 (2R,4a′R,8a′R)-3,7′-dimethyl- 41816-03-9 DEFHJK3′,4′,4a′,5′,8′,8a′-hexahydro-1′H- spiro[oxirane-2,2′-[1,4]methanonaphthalene] 1008 (Z)-6-ethylideneoctahydro-2H-5,8-93939-86-7 BCEFHJKL methanochromene 1009 2-((S)-1-((S)-3,3- 236391-76-7DFHJ dimethylcyclohexyl)ethoxy)-2- oxoethyl propionate 1010 Methyl2,2-dimethyl-6- 81752-87-6 ADHIJKL methylenecyclohexane-1-carboxylate1012 2-methyl-5-phenylpentan-1-ol 25634-93-9 DEFHJK 10164-methyl-2-phenyl-3,6-dihydro-2H-pyran 60335-71-9 BCEFGJK 1020 Sabinol471-16-9 BCEFHIJKL 1021 Safrole 94-59-7 BCEFHK 10222,2,7,9-tetramethylspiro(5.5)undec- 502847-01-0 DHIJK 8-en-1-one 10233-methyl-5-(2,2,3- 65113-99-7 DEFHJKtrimethylcyclopent-3-en-1-yl)pentan- 2-ol 1024 (Z)-2-ethyl-4-(2,2,3-28219-61-6 DEFHJK trimethylcyclopent-3-en-1-yl)but-2- en-1-ol 1025(E)-2-methyl-4-(2,2,3- 28219-60-5 CHJKtrimethylcyclopent-3-en-1-yl)but-2- en-1-ol 10265-methoxyoctahydro-1H-4,7- 86803-90-9 CHJK methanoindene-2-carbaldehyde1027 5-methoxyoctahydro-1H-4,7- 193425-86-4 CHJKmethanoindene-2-carbaldehyde 1028 Sclareol 515-03-7 DEFHJ 1029 Sclareoloxide 5153-92-4 DEFHJK 1031 Selina-3,7(11)-diene 6813-21-4 DEFHJKL 10322-(1-(3,3- 477218-42-1 DEFHJ dimethylcyclohexyl)ethoxy)-2-methylpropylcyclopropanecarboxylate 1033 3-(4-isobutylphenyl)-2- 6658-48-6 DHJKmethylpropanal 1035 Spathulenol 6750-60-3 DEFHJK 1036 Spirambrene533925-08-5 BCEFHJK 1037 Spirodecane 6413-26-9 BCEFGIJKL 10381-(spiro[4.5]dec-7-en-7-yl)pent-4-en-1-one 224031-70-3 DGJK 10422-(4-methylthiazol-5-yl)ethan-1-ol 137-00-8 CGIKL 10432-(heptan-3-yl)-1,3-dioxolane 4359-47-1 ACEFHIJKL 1045 (Z)-dodec-4-enal21944-98-9 BDFHJK 1046 tau-Cadinol 5937-11-1 DEFHJK 1047 tau-Muurolol19912-62-0 DEFHJK 1053 Tetrahydrojasmone 13074-63-0 BDFHIJKL 10572,6,10,10-tetramethyl-1- 36431-72-8 BDFHIJKL oxaspiro[4.5]dec-6-ene 1059Thiomenthone 38462-22-5 BDEFHIJKL 1060 Thujopsene 470-40-6 BDEFGJKL 1062Thymol methyl ether 1076-56-8 ADHIJKL 10631-(2,2,6-trimethylcyclohexyl)hexan-3-ol 70788-30-6 DEFHJK 1064trans,trans-2,4-Nonadienal 5910-87-2 ACHKL 1065 trans,trans-Farnesol106-28-5 DEFHJK 1066 trans-2,cis-6-Nonadienal 557-48-2 ACHKL 1067trans-2-Decenal 3913-81-3 ADHKL 1070 trans-2-Nonen-1-al 18829-56-6 ADHKL1072 trans-3, cis-6-nonadienol 56805-23-3 ACEFHK 1073 trans-4-Decen-1-al65405-70-1 ADHKL 1075 trans-ambrettolide 51155-12-5 DGJ 1077trans-beta-ocimene 13877-91-3 ADGIKL 1078 trans-beta-Ocimene 3779-61-1ADGIKL 1082 trans-Geraniol 106-24-1 BCHIK 1083 trans-Hedione 2570-03-8DFHJK 1085 7-(1,1-Dimethylethyl)-2H-1,5- 195251-91-3 CEFHJbenzodioxepin-3(4H)-one 1089 Tricyclone 68433-81-8 DEFHJK 1090 Tridecylalcohol 112-70-9 DEFGJK 1091 Triethyl citrate 77-93-0 CEFGJ 1093 Methyl2-((1-hydroxy-3- 144761-91-1 DFHJ phenylbutyl)amino)benzoate 10951-((2E,5Z,9Z)-2,6,10- 28371-99-5 DHJKtrimethylcyclododeca-2,5,9-trien-1- yl)ethan-1-one 1097Decahydro-2,6,6,7,8,8-hexamethyl- 338735-71-0 BDEFHJK2h-indeno(4,5-b)furan 1099 13-methyl oxacyclopentadec-10-en-2-one365411-50-3 DEFHJK 1102 Undecanal 112-44-7 BDHJK 1104(E)-4-methyldec-3-en-5-ol 81782-77-6 BDEFHIJK 1105 Valencene 4630-07-3BDEFHJK 1107 Valerianol 20489-45-6 DEFHJK 1111 Vanillin isobutyrate20665-85-4 CHJ 1113 Vaniwhite ® 5533-03-9 CGIK 1116(Z)-2-methyl-4-(2,6,6- 68555-62-4 BDFHJKtrimethylcyclohex-2-en-1-yl)but-2-enal 1117 Methyl 2,4-dihydroxy-3,6-4707-47-5 CGIJ dimethylbenzoate 1120 1-methoxy-3a,4,5,6,7,7a-hexahydro-27135-90-6 ACEFHJKL 1H-4,7-methanoindene 1121 Methyl (Z)-2-((3-(4-(tert-91-51-0 DFHJ butyl)phenyl)-2- methylpropylidene)amino)benzoate 1125(Z)-hex-3-en-1-yl isobutyrate 41519-23-7 ADEFHJKL 1126 Vertacetal5182-36-5 BCFHJK 1129 1-((3R,3aR,7R,8aS)-3,6,8,8- 32388-55-9 DHJKtetramethyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-methanoazulen-5-yl)ethan-1-one 1131 Methyl (Z)-2-(((2,4- 68738-99-8DEFHJ dimethylcyclohex-3-en-1- yl)methylene)amino)benzoate 1135Vetiverol 89-88-3 CEFHIJK 1136 Vetivert Acetate 117-98-6 DEFHJK 1137Decahydro-3H-spiro[furan-2,5′- 68480-11-5 DEFGJKL [4,7]methanoindene]1138 (2Z,6E)-nona-2,6-dienenitrile 67019-89-0 ACEFHKL 1139(Z)-cyclooct-4-en-1-yl methyl 87731-18-8 BCHJKL carbonate 1140(1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7- 552-02-3 DEFHJKtetramethyldecahydro-1H- cyclopropa[e]azulen-4-ol 11423,5,5,6,7,8,8-heptamethyl-5,6,7,8- 127459-79-4 DHJtetrahydronaphthalene-2-carbonitrile 1143 (1S,2S,3S,5R)-2,6,6-133636-82-5 DEFHJK trimethylspiro[bicyclo[3.1.1]heptane-3,1′-cyclohexan]-2′-en-4′-one 1144 1′,1′,5′,5′-tetramethylhexahydro-154171-76-3 DEFHJK 2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene] 1145 1′,1′,5′,5′-tetramethylhexahydro-154171-77-4 DEFHJK 2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene] K 1146 4-(4-hydroxy-3- 122-48-5 CEFGJmethoxyphenyl)butan-2-one 1147 (1R,8aR)-4-isopropyl-1,6-dimethyl-41929-05-9 DEFHJKL 1,2,3,7,8,8a-hexahydronaphthalene 11484,5-epoxy-4,11,11-trimethyl-8- 1139-30-6 DEFHJKmethylenebicyclo(7.2.0)undecane 1149 1,3,4,6,7,8alpha-hexahydro-1,1,5,5-23787-90-8 DEFHIJK tetramethyl-2H-2,4alpha- methanophthalen-8(5H)-one

TABLE 2 List of materials with at least one MORV greater than 5 to 10Num- CAS Comment ber Material Name Number Code 22,4-dimethyl-2-(5,5,8,8-tetramethyl- 131812-67-4 DFHJ5,6,7,8-tetrahydronaphthalen-2-yl)- 1,3-dioxolane 233a,5,6,7,8,8b-hexahydro- 823178-41-2 DEFHJK2,2,6,6,7,8,8-heptamethyl-4H- indeno(4,5-d)-1,3-dioxole 1412,4-dimethyl-4,4a,5,9b- 27606-09-3 CEFHJKtetrahydroindeno[1,2-d][1,3]dioxine 185 (1-methyl-2-((1,2,2- 198404-98-7DEFHJK trimethylbicyclo[3.1.0]hexan-3- yl)methyl)cyclopropyl)methanol227 Isobornylcyclohexanol 68877-29-2 DEFHJK 230 Isobornyl cyclohexanol66072-32-0 DEFHJK 246 Indol/Hydroxycitronellal Schiff base 67801-36-9DEFHJ 248 Hydroxymethyl isolongifolene 59056-64-3 DEFHJK 3438,8-dimethyl-3a,4,5,6,7,7a- 76842-49-4 DEFHJKhexahydro-1H-4,7-methanoinden-6- yl propionate 359(E)-4-((3aR,4R,7R,7aR)- 501929-47-1 DEFHJK1,3a,4,6,7,7a-hexahydro-5H-4,7- methanoinden-5-ylidene)-3-methylbutan-2-ol 565 Cedryl methyl ether 19870-74-7 BDEFHJK 631beta-Copaene 18252-44-3 BDEFHJKL 659 2′-isopropyl-1,7,7- 869292-93-3BDEFHJK trimethylspiro[bicyclo[2.2.1]heptane- 2,4′-[1,3]dioxane] 674(4aR,5R,7aS,9R)-2,2,5,8,8,9a- 211299-54-6 DEFHJKhexamethyloctahydro-4H-4a,9- methanoazuleno[5,6-d][1,3]dioxole 678(3S,5aR,7aS,11aS,11bR)-3,8,8,11a- 57345-19-4 DEFHJtetramethyldodecahydro-5H-3,5a- epoxynaphtho[2,1-c]oxepine 6792,2,6,6,7,8,8-heptamethyldecahydro- 476332-65-7 DEFHJK2H-indeno[4,5-b]furan 715 alpha-Cedrene epoxide 13567-39-0 BDEFHJK 758Acetoxymethyl-isolongifolene 59056-62-1 DEFHJK (isomers) 1028 Sclareol515-03-7 DEFHJ 1097 Decahydro-2,6,6,7,8,8-hexamethyl- 338735-71-0 DEFHJK2h-indeno(4,5-b)furan

TABLE 3 List of materials with at least one MORV from 0.5 to less than 1Num- CAS Comment ber Material Name Number Code 12 1-ethoxy-4-(tert-181258-89-9 ADEFHJK pentyl)cyclohexane 19 (3Z)-1-(2-buten-1-yloxy)-3-888744-18-1 ADEFHJKL hexene 20 4-(2-methoxypropan-2-yl)-1- 14576-08-0ADHIJKL methylcyclohex-1-ene 24 O-Methyl linalool 60763-44-2 ADHIJKL 26o-Methoxycinnamaldehyde 1504-74-1 ACHK 27 Octanal, 3,7-dimethyl-25795-46-4 ADGIJKL 53 3,3-Dimethyl-5(2,2,3- 329925-33-9 CEFHJTrimethyl-3-Cyclopenten- 1yl)-4-Penten-2-ol 54 n-Hexyl salicylate6259-76-3 DEFHJ 55 n-Hexyl 2-butenoate 19089-92-0 ADEFHJKL 59 NerylFormate 2142-94-1 BCEFHJK 72 Methyl-beta-ionone 127-43-5 DHJK 73Myroxide 28977-57-3 ADGIJKL 81 (E)-3,7-dimethylocta-4,6- 18479-54-4BCEFGIJK dien-3-ol 84 (Z)-hex-3-en-1-yl 188570-78-7 BCEFHIKLcyclopropanecarboxylate 96 Methyl phenyl carbinyl 120-45-6 BCHJKpropionate 97 Methyl phenylacetate 101-41-7 ACEFHIKL 107 2-methyl-6-91069-37-3 BCEFGIKL oxaspiro[4.5]decan-7-one 111 Methyl geraniate2349-14-6 BCHJKL 115 2-ethoxy-4- 5595-79-9 CFGK (methoxymethyl)phenol116 Methyl 40203-73-4 ACEFHIKL cyclopentylideneacetate 125Methoxymelonal 62439-41-2 ACGIJK 133 ((1s,4s)-4- 13828-37-0 BDEFHIJKisopropylcyclohexyl)methanol 147 Linalyl propionate 144-39-8 BDFHJK 150Linalyl formate 115-99-1 ACFHJK 151 Linalyl butyrate 78-36-4 BDEFHJK 154Linalyl acetate 115-95-7 BDHJK 157 Linalool 78-70-6 BCEFGIJK 163(Z)-hex-3-en-1-yl methyl 67633-96-9 ACEFGKL carbonate 166 Lepidine491-35-0 BCEFHIKL 169 L-Carvone 6485-40-1 ACGIJKL 181 Khusinil75490-39-0 DHJK 191 Isoraldeine 1335-46-2 BDHIJK 194Isopropylvinylcarbinol 4798-45-2 ACGIKL 198 Isopropyl 2-methylbutyrate66576-71-4 ACEFGIJKL 201 Isopentyrate 80118-06-5 ADEFGIJKL 204 Isononylacetate 40379-24-6 BDEFHJKL 205 Isononanol 27458-94-2 BDEFGIKL 213Isoeugenyl acetate 93-29-8 CFHJK 214 Isoeugenol 97-54-1 CEFHIK 232Isoborneol 124-76-5 ACEFHIJKL 237 Isoamyl octanoate 2035-99-6 DEFHJK 239Isoamyl isobutyrate 2050-01-3 ACEFGIJKL 255 Hydrocinnamic acid 501-52-0CEFHIK 258 Hydratopic alcohol 1123-85-9 BCEFHIK 264 Hexyl propanoate2445-76-3 ADEFHIKL 270 Hexyl butyrate 2639-63-6 BDEFHJKL 273 Hexyl2-methylbutanoate 10032-15-2 BDEFHJKL 275 Hexyl 2-furoate 39251-86-0DEFHJK 282 Heptyl alcohol 111-70-6 ACEFGIKL 283 Heptyl acetate 112-06-1ADEFHKL 284 Heptaldehyde 111-71-7 ACHIKL 287 Heliotropin 120-57-0 BCGIK302 Geranyl nitrile 5146-66-7 BCEFHKL 306 Geranyl formate 105-86-2BCEFHJK 308 Geranyl caprylate 51532-26-4 DEFHJ 310 Geranyl benzoate94-48-4 DFHJ 312 Geranial 141-27-5 ACHIKL 314 N,2-dimethyl-N- 84434-18-4BCEFHJK phenylbutanamide 319 gamma-Terpinene 99-85-4 ADEFGIJKL 3462-(sec-butyl)cyclohexan-1- 14765-30-1 ADFHIKL one 3543-(2-ethylphenyl)-2,2- 67634-14-4 BDHJK dimethylpropanal 3552-(tert-butyl)cyclohexyl ethyl 67801-64-3 BDFHJK carbonate 3652-(tert-butyl)cyclohexyl ethyl 81925-81-7 ACFHIKL carbonate 366 Fenchylalcohol 1632-73-1 ACGIJKL 376 Eucalyptol 470-82-6 ADEFGIJKL 379 Ethylvanillin acetate 72207-94-4 CHJ 387 Ethyl octanoate 106-32-1 BDEFHJKL400 Ethyl cinnamate 103-36-6 BCEFHK 412 Ethyl 2- 2511-00-4 BDFHIJKL(cyclohexyl)propionate 419 d-p-8(9)-Menthen-2-one 5524-05-0 ACGIJKL 4204-methyl-2-phenyltetrahydro- 94201-73-7 BDEFHJK 2H-pyran 437Dihydromyrcenol 18479-58-8 ADEFGIJK 438 Dihydrojasmone 1128-08-1BCFHIJKL 439 Dihydroisophorone 873-94-9 ACEFGIJKL 440 Dihydroeugenol2785-87-7 CEFHIJK 442 Dihydrocoumarin 119-84-6 BCGIKL 443 Dihydrocarvone7764-50-3 ACGIJKL 447 Dihydro-alpha-terpinyl 80-25-1 BDEFHIJKL acetate448 Dihydro-alpha-ionone 31499-72-6 BDHIJK 454 Dibenzyl ether 103-50-4DEFHJK 455 Dibutyl o-phthalate 84-74-2 DEFHJ 4692-pentylcyclopentan-1-one 4819-67-4 BDFHIKL 472 Decyl anthranilate18189-07-6 DEFHJ 477 Methyl (1s,4s)-1,4- 23059-38-3 ADEFHIJKLdimethylcyclohexane-1- carboxylate 481 Cyclohexylethyl acetate21722-83-8 BDEFHJKL 492 Creosol 93-51-6 BCHIK 495 Cosmene 460-01-5ADEFGIKL 496 4-cyclohexyl-2-methylbutan- 83926-73-2 BDEFGIJK 2-ol 5042-benzyl-2-methylbut-3- 97384-48-0 BDHJK enenitrile 509 Citronellylnitrile 51566-62-2 BCEFGIKL 510 Citronellyl phenylacetate 139-70-8 DFHJ512 Citronellyl formate 105-85-1 BCEFGJKL 515 Citronellyl benzoate10482-77-6 DFHJ 517 Citronellol 106-22-9 BCHIJKL 518 Citronellal106-23-0 ACHIJKL 522 Citral 5392-40-5 ACHIKL 525 cis-Pinane 6876-13-7ADEFGIJKL 526 (Z)-3-methyl-2-(pent-2-en-1- 488-10-8 BCHIJKLyl)cyclopent-2-en-1-one 528 cis-iso-Eugenol 5912-86-7 CEFHIK 535cis-3-Hexenyl valerate 35852-46-1 BDEFHJKL 536 cis-3-Hexenyl tiglate67883-79-8 BDEFHJK 538 cis-3-Hexenyl propionate 33467-74-2 ACEFHIKL 540cis-3-Hexenyl butyrate 16491-36-4 ADEFHJKL 542 cis-3-Hexen-1-ol 928-96-1ACEFHIKL 547 cis-2-Hexenol 928-94-9 ACEFHIKL 549 Cinnamyl nitrile4360-47-8 ACEFGIK 554 Cinnamic aldehyde 104-55-2 ACHIK 556 Cinnamylnitrile 1885-38-7 ACEFGIK 557 Chloroxylenol 88-04-0 BCHIJK 575 Carvacrol499-75-2 DHIJK 576 Carvone 99-49-0 ACGIJKL 579 Carbitol 111-90-0 BCEFGIK583 Caproyl alcohol 111-27-3 ACEFGIKL 585 2-(2,2,3-trimethylcyclopent-3-15373-31-6 ACGIJKL en-1-yl)acetonitrile 588 Camphor 76-22-2 ACEFGIJKL602 (E)-2-methyl-4-(2,6,6- 3155-71-3 DHJK trimethylcyclohex-1-en-1-yl)but-2-enal 605 Borneol 507-70-0 ACEFHIJKL 617 beta-Pinene epoxide6931-54-0 ACEFGIJKL 619 beta-Phellandrene 555-10-2 ADEFGIJKL 640Benzylacetone 2550-26-7 ACEFGIK 641 Benzyl salicylate 118-58-1 DFGJ 645Benzyl isovalerate 103-38-8 BDEFHJK 647 Benzyl isobutyrate 103-28-6BCHJK 651 Benzyl butyrate 103-37-7 BCEFHJK 652 Benzyl alcohol 100-51-6ACEFGIKL 662 1-(3,3- 25225-08-5 ADEFHIJKL dimethylcyclohexyl)ethylformate 664 Anisyl acetate 104-21-2 BCEFGK 665 Anisyl formate 122-91-8BCEFGK 667 Anethole 104-46-1 ACEFHK 672 Amyl benzoate 2049-96-9 DEFHJK687 alpha-Terpinyl acetate 80-26-2 BDHJK 699 alpha-methyl- 10528-67-3BDEFHIK cyclohexanepropanol 701 alpha-methyl cinnamaldehyde 101-39-3ACHIK 703 alpha-Isomethylionone 127-51-5 BDHIJK 7402,5-Dimethyl-4-methoxy- 4077-47-8 ACEFGIJKL 3(2H)-furanone 743 Allylphenoxyacetate 7493-74-5 BCGK 744 Allyl Phenethyl ether 14289-65-7ACEFHK 745 Allyl heptanoate 142-19-8 ADEFHJKL 755 N-ethyl-N-(m-179911-08-1 CEFHJK tolyl)propionamide 760 3-hydroxybutan-2-one 513-86-0ACEFGIKL 761 Acetoanisole 100-06-1 BCEFHIK 777 6-Methylquinoline 91-62-3BCEFHIKL 779 6,8-Diethyl-2-nonanol 70214-77-6 BDEFGIJKL 7845-Methyl-3-heptanone 541-85-5 ACFGIKL 789 4-Vinylphenol 2628-17-3 BCHIK796 4-hydroxy-3-methoxy- 458-36-6 CH cinnamaldehyde 797 4-Ethylguaiacol2785-89-9 CEFHIK 799 4-Damascol 4927-36-0 BDFHJK 8083-methyl-4-phenylpyrazole 13788-84-6 CEFHK 810 3-Methyl-1,2- 765-70-8ACEFGIKL cyclopentanedione 811 3-Methoxy-5-methylphenol 3209-13-0 BCHIK812 3-Methoxy-3-Methyl Butanol 56539-66-3 ACGIKL 817 3-Hexenol 544-12-7ACEFHIKL 819 3,7-dimethyl-2-methylene-6- 22418-66-2 ADFHIJK octenal 8203,7-dimethyl-1-octanol 106-21-8 BDEFGIJKL 832 2-Phenylethyl acetate103-45-7 BCEFHK 835 2-Phenethyl propionate 122-70-3 BCEFHJK 8362-Pentylcyclopentan-1-ol 84560-00-9 DEFHIKL 838 2-nonanone propyleneglycol 165191-91-3 BDEFHJK acetal 845 2-Methoxy-3-(1- 24168-70-5 BCEFGIKmethylpropyl)pyrazine 846 2-isopropyl-N,2,3- 51115-67-4 ACEFGIJKtrimethylbutyramide 847 2-Isopropyl-5-methyl-2- 35158-25-9 ADFGIJKLhexenal 848 2-Isopropyl-4-methylthiazole 15679-13-7 ACHIJKL 8512-Hexen-1-ol 2305-21-7 ACEFHIKL 858 2-Butoxyethanol 111-76-2 ACEFGIKL875 1,4-Cineole 470-67-7 ADGIJKL 880 1-(2,6,6-Trimethyl-2- 43052-87-5BDHIJK cyclohexen-1-yl)-2-buten-1- one 882 (Z)-3-hepten-1-yl acetate1576-78-9 ACEFHKL 883 (S)-(1R,5R)-4,6,6- 1196-01-6 ACEFGIJKLtrimethylbicyclo[3.1.1]hept-3- en-2-one 888 (R)-(−)-Linalool 126-91-0BCEFGIJK 889 (l)-Citronellal 5949-05-3 ACHIJKL 891 (d)-Citronellal2385-77-5 ACHIJKL 899 (+)-Citronellol 1117-61-9 BCHIJKL 900(−)-Citronellol 7540-51-4 BCHIJKL 901 (+)-alpha-Pinene 7785-70-8ADEFGIJKL 902 (+)-Carvone 2244-16-8 ACGIJKL 903 (−)-alpha-Pinene7785-26-4 ADEFGIJKL 904 Methyl 2-methylbutyrate 868-57-5 ACEFGIKL 909Hexyl tiglate 16930-96-4 BDEFHJKL 918 Allyl 2- 68901-15-5 CHJK(cyclohexyloxy)acetate 921 1,5- 75147-23-8 CFHIJKdimethylbicyclo[3.2.1]octan- 8-one oxime 931 alpha-acetoxystyrene2206-94-2 ACEFHIK 940 p-Cymene 99-87-6 ADGIJKL 956 Phenethyl formate104-62-1 ACEFHK 958 Phenethyl isobutyrate 103-48-0 DHJK 960 Phenethyltiglate 55719-85-2 DHJK 971 Phenylethyl methacrylate 3683-12-3 DHJK 977p- 4395-92-0 BDFHK Isopropylphenylacetaldehyde 9811,2-dimethyl-3-(prop-1-en-2- 72402-00-7 BCEFGIJKL yl)cyclopentan-1-ol983 p-Methoxyphenylacetone 122-84-9 BCEFHK 986(2Z,5Z)-5,6,7-trimethylocta- 358331-95-0 ADHIJKL 2,5-dien-4-one 987p-Propyl anisole 104-45-0 ADEFHKL 994 p-t-butyl phenyl acetaldehyde109347-45-7 BDHJK 995 p-tert-Amyl cyclohexanol 5349-51-9 BDEFHIJK 1001Racemic alpha-Pinene 80-56-8 ADEFGIJKL 1002 4-(4-hydroxyphenyl)butan-2-5471-51-2 CEFGIK one 1004 Rhodinol 141-25-3 BCHIJKL 1005 Ethyl (2,3,6-93981-50-1 BDEFHJKL trimethylcyclohexyl) carbonate 1011 1-(3,3-25225-10-9 ADHIJKL dimethylcyclohexyl)ethyl acetate 1017 S)-(+)-Linalool126-90-9 BCEFGIJK 1018 Sabinene 3387-41-5 ADEFGIJKL 1019 Sabinenehydrate 546-79-2 ADEFGIJKL 1030 Propyl (S)-2-(tert- 319002-92-1 BDEFHJKpentyloxy)propanoate 1039 Spirolide 699-61-6 BCGIKL 1040(Z)-5-methylheptan-3-one 22457-23-4 BCEFGIJKL oxime 1041 1-phenylethylacetate 93-92-5 ACEFHIK 1051 Tetrahydrogeranial 5988-91-0 ADGIJKL 1052Tetrahydroionol 4361-23-3 BDEFHIJK 1054 Tetrahydrolinalool 78-69-3BDEFGIJKL 1055 Tetrahydrolinalyl acetate 20780-48-7 ADEFHJKL 1058 Ethyl(1R,6S)-2,2,6- 22471-55-2 ADEFHIJKL trimethylcyclohexane-1- carboxylate1061 Thymol 89-83-8 BDHIJK 1069 trans-2-Hexenol 928-95-0 ACEFHIKL 1071trans-2-tert- 5448-22-6 ACGIJKL Butylcyclohexanol 1074trans-alpha-Damascone 24720-09-0 BDHIJK 1076 trans-Anethole 4180-23-8ACEFHK 1079 trans-Cinnamic acid 140-10-3 CEFHK 1081 trans-Dihydrocarvone5948-04-9 ACGIJKL 1084 trans-Isoeugenol 5932-68-3 CEFHIK 1088Trichloromethyl phenyl 90-17-5 BDEFGJ carbinyl acetate 10982-mercapto-2-methylpentan- 258823-39-1 ACEFHIJKL 1-ol 1110 Vanillinacetate 881-68-5 CH 1112 Vanitrope 94-86-0 CEFHK 1115 2,2,5-trimethyl-5-65443-14-3 BDFGIJKL pentylcyclopentan-1-one 1118 Veratraldehyde 120-14-9BCGIK 1119 (1R,5R)-4,6,6- 18309-32-5 ACEFGIJKLtrimethylbicyclo[3.1.1]hept-3- en-2-one 1122 Verdol 13491-79-7 ACGIJKL1127 4-(tert-butyl)cyclohexyl 10411-92-4 BDEFHJK acetate 11284-(tert-butyl)cyclohexyl 32210-23-4 BDEFHJK acetate 1133 Vethymine7193-87-5 CEFGK 1134 4-methyl-4-phenylpentan-2-yl 68083-58-9 BDFHJKacetate 1141 (Z)-1-((2- 292605-05-1 ADEFHKL methylallyl)oxy)hex-3-ene

TABLE 4 List of materials with ALL MORVs from 1 to 5 Num- CAS Commentber Material Name Number Code 7 3-methoxy-7,7-dimethyl-10- 216970-21-7BDEFHJK methylenebicyclo[4.3.1]decane 14 Oxyoctaline formate 65405-72-3DFHJK 39 2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a- 103614-86-4 DEFHIJKoctahydronaphthalen-1-ol 48 Nootkatone 4674-50-4 DHJK 183 Khusimol16223-63-5 CEFHJK 199 Isopimpinellin 482-27-9 CFGJ 206Iso3-methylcyclopentadecan-1-one 3100-36-5 DEFGJK 212 Isoeugenyl benzylether 120-11-6 DFHJ 215 1-((2S,3S)-2,3,8,8-tetramethyl- 54464-57-2 DHJK1,2,3,4,5,6,7,8-octahydronaphthalen- 2-yl)ethan-1-one 229 Isobornylisobutyrate 85586-67-0 BDEFHIJK 260 2,3-dihydro-3,3-dimethyl-1H-indene-173445-44-8 DHJK 5-propanal 261 3-(3,3-dimethyl-2,3-dihydro-1H-173445-65-3 DHJK inden-5-yl)propanal 281 3a,4,5,6,7,7a-hexahydro-1H-4,7-5413-60-5 CEFGJK methanoinden-6-yl acetate 329 gamma-Eudesmol 1209-71-8DFHJK 335 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8- 1222-05-5 DEFHJKhexahydrocyclopenta[g]isochromene 353 (Z)-6-ethylideneoctahydro-2H-5,8-69486-14-2 CEFGJK methanochromen-2-one 360 8,8-dimethyl-3a,4,5,6,7,7a-171102-41-3 DEFHJK hexahydro-1H-4,7-methanoinden-6- yl acetate 441Octahydro-1H-4,7-methanoinden-5- 64001-15-6 DEFHJKL yl acetate 4843a,4,5,6,7,7a-hexahydro-1H-4,7- 113889-23-9 DEFHJK methanoinden-6-ylbutyrate 487 3a,4,5,6,7,7a-hexahydro-1H-4,7- 67634-20-2 DEFHJKmethanoinden-5-yl isobutyrate 488 Curzerene 17910-09-7 DHJK 501(E)-cycloheptadec-9-en-1-one 542-46-1 DEFGJ 566 Cedryl formate39900-38-4 BDEFHJK 567 Cedryl acetate 77-54-3 DEFHJK 569 Cedrol 77-53-2DEFHJK 570 5-methyl-1-(2,2,3- 139539-66-5 DEFHJKtrimethylcyclopent-3-en-1-yl)-6- oxabicyclo[3.2.1]octane 573Caryophyllene alcohol acetate 32214-91-8 DEFHJK 574 Caryolan-1-ol472-97-9 DEFHJK 603 Bornyl isobutyrate 24717-86-0 BDEFHIJK 616beta-Santalol 77-42-9 DEFHJK 621 beta-Patchoulline 514-51-2 BDEFGJKL 624beta-Himachalene Oxide 57819-73-5 BDFHJK 627 (2,2-dimethoxyethyl)benzene101-48-4 DHJK 632 beta-Cedrene 546-28-1 BDEFGJKL 663 Anisylphenylacetate 102-17-0 DFHJ 680 2,2,6,6,7,8,8-heptamethyldecahydro-647828-16-8 ADEFHJK 2H-indeno[4,5-b]furan 684 alpha-Vetivone 15764-04-2DHJK 694 alpha-Santalol 115-71-9 DEFHJK 696 alpha-Patchoulene 560-32-7ADEFHJKL 708 alpha-Gurjunene 489-40-7 BDEFHJKL 712 alpha-Eudesmol473-16-5 DEFHJK 714 alpha-Cubebene 17699-14-8 ADEFHJKL 726alpha-Agarofuran 5956-12-7 BDEFHJK 750 Allo-aromadendrene 25246-27-9BDEFHJKL 764 Acetarolle 744266-61-3 DFHJK 775 7-eip-alpha-Eudesmol123123-38-6 DEFHJK 776 7-Acetyl-1,1,3,4,4,6- 1506-02-1 DEFHJhexamethyltetralin 788 5-Cyclohexadecenone 37609-25-9 DEFGJK 8043-Thujopsanone 25966-79-4 BDEFHJK 872 10-epi-gamma-Eudesmol 15051-81-7DFHJK 919 3a,4,5,6,7,7a-hexahydro-1H-4,7- 17511-60-3 CEFHJKmethanoinden-6-yl propionate 927 5-Acetyl-1,1,2,3,3,6- 15323-35-0 DEFHJKhexamethylindan 933 Patchouli alcohol 5986-55-0 DEFHIJK 9783a,4,5,6,7,7a-hexahydro-1H-4,7- 68039-44-1 DEFHJK methanoinden-6-ylpivalate 1007 (2R,4a′R,8a′R)-3,7′-dimethyl- 41816-03-9 DEFHJK3′,4′,4a′,5′,8′,8a′-hexahydro-1′H- spiro[oxirane-2,2′-[1,4]methanonaphthalene] 1022 2,2,7,9-tetramethylspiro(5.5)undec-502847-01-0 DHIJK 8-en-1-one 1024 (Z)-2-ethyl-4-(2,2,3- 28219-61-6DEFHJK trimethylcyclopent-3-en-1-yl)but-2- en-1-ol 10275-methoxyoctahydro-1H-4,7- 193425-86-4 CHJK methanoindene-2-carbaldehyde1029 Sclareol oxide 5153-92-4 DEFHJK 1035 Spathulenol 6750-60-3 DEFHJK1038 1-(spiro[4.5]dec-7-en-7-yl)pent-4-en- 224031-70-3 DGJK 1-one 1060Thujopsene 470-40-6 BDEFGJKL 1089 Tricyclone 68433-81-8 DEFHJK 1107Valerianol 20489-45-6 DEFHJK 1129 1-((3R,3aR,7R,8aS)-3,6,8,8- 32388-55-9DHJK tetramethyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-methanoazulen-5-yl)ethan- 1-one 1131 Methyl (Z)-2-(((2,4-68738-99-8 DEFHJ dimethylcyclohex-3-en-1- yl)methylene)amino)benzoate1136 Vetivert Acetate 117-98-6 DEFHJK 1137Decahydro-3H-spiro[furan-2,5′- 68480-11-5 DEFGJKL [4,7]methanoindene]1140 (1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7- 552-02-3 DEFHJKtetramethyldecahydro-1H- cyclopropa[e]azulen-4-ol 11423,5,5,6,7,8,8-heptamethyl-5,6,7,8- 127459-79-4 DHJtetrahydronaphthalene-2-carbonitrile 1143 (1S,2S,3S,5R)-2,6,6-133636-82-5 DEFHJK trimethylspiro[bicyclo[3.1.1]heptane-3,1′-cyclohexan]-2′-en-4′-one 1144 1′,1′,5′,5′-tetramethylhexahydro-154171-76-3 DEFHJK 2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene] 1145 1′,1′,5′,5′-tetramethylhexahydro-154171-77-4 DEFHJK 2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene] K 1148 4,5-epoxy-4,11,11-trimethyl-8-1139-30-6 DEFHJK methylenebicyclo(7.2.0)undecane 11491,3,4,6,7,8alpha-hexahydro-1,1,5,5- 23787-90-8 DEFHIJKtetramethyl-2H-2,4alpha- methanophtalen-8(5H)-one

TABLE 5 List of materials with ALL MORVs greater than 5 to 10 Num- CASComment ber Material Name Number Code 248 Hydroxymethyl 59056-64-3BDEFHJK isolongifolene

TABLE 6 List of materials with ALL MORVs from 0.5 to less than 1 Num-CAS Comment ber Material Name Number Code 472 Decyl anthranilate18189-07-6 DEFHJ 526 (Z)-3-methyl-2-(pent- 488-10-8 BCHIJKL2-en-1-yl)cyclopent- 2-en-1-oneThe materials in Tables 1-6 can be supplied by one or more of thefollowing:Firmenich Inc. of Plainsboro N.J. USA; International Flavor andFragrance Inc. New York, N.Y. USA; Takasago Corp. Teterboro, N.J. USA;Symrise Inc. Teterboro, N.J. USA; Sigma-Aldrich/SAFC Inc. Carlsbad,Calif. USA; and Bedoukian Research Inc. Danbury, Conn. USA.Actual MORV values for each material listed in Tables 1-6 above are asfollows:

MORV MORV MORV MORV Material value for Value for Value for value for No.Equation a.) Equation b.) Equation c.) Equation d.) 1 0.5482239140.876283261 1.22018588 −0.41901144 2 1.520311929 3.493450446 2.706572655.11342862 3 2.267801995 −0.81712657 0.43218875 1.595983683 4−0.591063369 −0.48283571 0.16199804 1.210497701 7 1.4374446362.131822996 3.81633465 1.318339345 9 2.151445882 −0.46189495 0.560904691.206360803 10 2.5733592 −0.58780849 1.39751471 1.258361951 113.052627325 1.008519135 −0.30475953 0.076323462 12 0.683776599−0.01157903 0.82853231 0.326169402 13 1.549643217 1.809183231 0.708645312.22799611 14 2.82111224 2.339505033 1.240818 2.502429355 16 −0.31551128−0.06816599 −0.04371934 2.76742389 17 −1.334904153 −0.5773313 1.756447981.898455724 18 −1.34154226 −2.63596666 0.06885109 1.001431671 190.15532384 0.09866097 0.64214585 −0.33330779 20 0.640261783 0.6932132680.54637273 −0.97556029 21 0.936895364 −0.01521118 1.1697513 −0.6351080922 1.158981042 1.115900089 −0.25859776 1.318200884 23 3.7023610741.399942641 5.23954766 7.089933671 24 0.773874141 0.146848137−1.05705847 −0.36193173 25 −1.016103969 −1.18967936 0.780646252.944710012 25 −1.016103969 −1.18967936 0.78064625 2.944710012 260.615085491 −0.00096877 −0.35697252 −0.18121401 27 0.70261974−0.22197386 0.19710806 −2.37196477 28 1.366472597 −0.42546942−0.59394241 −0.01417395 29 1.096043453 −1.02972898 −1.42167356−0.63817943 30 1.143415203 −0.85945441 −0.41416913 2.499807942 311.138642907 −0.19595476 −0.54547769 −0.98828898 32 1.914414495−0.64487788 0.63212987 1.166699371 33 0.314847366 1.848003955 −1.3905032−0.62848261 34 −0.113542761 0.981530917 0.32824239 1.126524277 350.472382903 1.494882467 −0.07201236 −0.64589543 36 3.1585137951.084094934 −0.00328981 −0.17786385 37 −1.055631982 2.2401729640.92596118 2.105391988 38 3.158513795 0.592820874 −0.493262410.212867212 39 1.083800659 2.069727985 2.48170879 3.205630609 42−0.103134861 0.267726008 −0.65350189 1.125952363 43 0.3239616281.469295081 −0.52991193 0.797908251 47 1.703678841 1.3487370952.00634162 −0.16505407 48 2.370955056 2.783472865 2.68240273 1.22186440549 1.670680003 −0.41866107 −0.9173849 1.181929544 50 1.6706800030.076369374 −0.49915943 −0.85392575 52 0.464485039 0.0575128691.31230219 −0.11170276 53 0.626671823 −0.46954947 −0.333837360.277079201 54 0.666149043 0.009549925 −0.36226343 0.197224432 550.723473579 −1.50916383 −0.3848989 −0.71458778 57 0.3812732271.192994109 1.65593321 −1.65739236 59 0.561360663 −0.17793966−1.63250554 −0.7564969 61 0.146473611 −0.01535544 −0.163396581.738656146 62 1.20162032 −0.3576095 −0.10695443 1.322155191 631.084291915 2.258720158 −1.01245416 1.688283974 64 0.7447706650.155243763 −1.8029919 1.023503542 65 0.972835178 2.797151284 1.534535790.857051645 67 2.069410561 0.021831924 0.37855159 −0.67235457 680.527636614 0.590831983 1.02843762 2.208655795 69 2.1339656912.088998449 2.05751412 −0.9433713 70 0.327378959 0.996844599 1.23648533−1.25138371 71 1.40093669 0.778222691 0.70401172 −0.24075444 720.617697349 −0.29503359 0.52404847 0.816184656 73 0.6177924730.888976061 −0.45289639 0.615659244 74 1.437359024 1.5482921470.10314807 −0.48982286 75 −1.970885622 3.398008325 4.08025266−0.89948156 76 −1.32746934 −2.65365233 0.10272816 1.001614125 77−2.541686116 3.295534192 3.75284227 0.404837808 78 −2.110794 2.1098747463.13350902 −0.3880285 79 1.641162056 −0.28533994 1.53676145 0.65269602380 1.594400214 0.283682865 2.23140233 1.111682021 81 0.176566806−2.0786518 −2.13986952 0.981126964 82 0.980373758 −0.28813159 0.194045011.252564677 83 0.941833098 0.317310013 1.17606727 0.72992237 840.774237336 −0.27140727 0.72461427 −1.56415746 85 2.0929769650.810644229 0.82999192 −0.62861806 91 2.061595915 −0.79930338−0.18285395 −0.66898499 92 2.068748434 −0.24299896 0.07214682−1.11758276 93 −0.08984279 −1.06025959 −0.05068694 1.560050105 960.927758203 −0.44129515 0.89190422 0.744284978 97 0.658667572−0.68771072 0.46051026 −0.53120883 98 0.853222693 −0.2037738 −0.214144411.119784962 100 1.654535066 0.995056228 2.35139085 0.543654824 1012.173663649 −0.11491477 1.48285148 1.698527571 102 2.066679492−0.16785146 −0.84780149 0.12159477 103 2.335152618 −0.028665850.16993375 −0.98254522 104 2.760588276 0.459513599 1.353102410.000336976 105 1.654535066 3.654489674 3.13033965 0.544225478 1061.750588169 −0.55853348 0.50257773 1.630011313 107 0.8967898630.73615897 0.53011623 −0.54697747 108 0.532375207 0.826537134 1.210403120.690230716 109 2.407655187 0.742651426 1.80322099 0.271832856 1100.54830833 2.916795026 1.40126098 0.690230716 111 0.939597126 −0.3750368−1.23479972 −0.89366351 112 1.398518854 1.265740274 4.19618377−0.12762692 113 1.415726941 0.086297006 3.43559555 −0.12964168 115−1.557729423 −0.44113526 0.86330536 0.590708892 116 0.193562268−1.58091165 0.83247813 −0.70978039 117 1.353510875 −0.59062398−0.31776345 −0.3050158 119 0.830052725 2.28725579 0.38409695 0.219336109120 1.261997955 −0.22622961 −1.04772194 2.028504137 122 1.505653628−1.14748206 −0.19760084 −0.81373045 123 −0.658721962 −0.212998781.01439841 −0.76731016 125 0.749676998 −1.0761601 0.99563924 −1.15409002126 0.931054384 −0.35067079 1.06050832 −1.62171794 128 −1.344832644−0.09451199 1.19145467 1.621274257 130 1.153249538 1.6050707082.38047907 −0.93842293 133 0.840066046 0.2323025 0.19054023 −0.26588341134 0.522267541 0.824106618 1.83479545 0.364403434 135 2.1428178872.142411243 −0.93830995 0.696522652 137 3.052627325 3.6062701660.50445208 0.076323462 140 −0.153437637 0.246303216 0.765657581.800968868 141 2.067620311 1.424830396 2.33536931 7.644025075 1420.98353103 1.950251373 2.50851828 −0.24499521 143 1.7369697250.991537809 2.5691601 1.227191656 145 −0.211768579 1.46336231−0.93580247 −1.48749449 146 1.912710035 0.926306508 1.812533330.494121361 147 0.675736703 0.99202385 −0.66034472 −0.66302669 1480.757176542 1.83006252 0.16210659 0.243674851 149 0.4387723711.091438092 −0.1560319 −0.61711642 150 0.84399938 0.675302022−1.69771411 −0.73841711 151 0.633570539 0.988413715 −0.54991825−0.43550324 152 0.911582356 1.974700218 −0.92267786 0.628660087 1530.319053885 2.531735341 −0.39139184 0.734629224 154 0.7148145120.690769753 −2.06588692 −0.73356628 155 −0.161798388 0.032135767−0.13802086 1.734928461 156 −0.571799976 −1.32834264 −1.653460171.856689553 157 0.131224024 0.21510779 −1.70996346 0.964902175 1581.201616145 −0.21158932 −0.8501176 −0.33330779 159 0.8112899081.606645397 0.25352447 −1.83775117 159 0.811289908 1.6066453970.25352447 −1.83775117 161 0.475184006 1.99305646 1.90910177 3.288337059162 0.833030517 0.487189028 1.76798642 0.104378164 163 0.58993703−0.46431772 0.74883588 −0.81090824 166 −0.121286831 −0.84664528−0.32625341 0.778055656 167 0.846400186 −0.25922232 0.692487741.183696217 168 −0.310930833 −0.81048493 0.08527131 1.61831109 169−0.2346025 0.890438419 −0.13206526 −0.83961838 170 −0.1692236951.172917966 −0.11306441 0.099121666 174 2.863652137 0.236674094−0.69038707 1.610215283 175 1.789769228 −0.31740428 −0.89529921−0.09686469 176 2.625947334 0.083548191 0.30634559 −0.35925728 1771.674319352 −0.22179044 0.42093738 −0.23683577 178 2.8636521370.727069168 −0.26724686 −0.44888613 179 0.070511885 0.3658528641.35327505 −0.03748038 181 0.976254543 0.691638796 0.51371978−0.02503945 182 −1.842503751 −0.12688474 2.56277877 0.111744488 1833.195758563 3.886545621 4.29482769 3.829845293 184 0.333889534−0.67236766 2.21605977 4.254612125 185 5.61162203 1.40458529 2.862313431.035135749 186 1.068190511 −0.65969343 −0.63104765 −1.36962992 1871.396358739 0.249705611 0.81449499 −0.15353102 189 1.544466636−0.33742685 0.8096674 −0.44483677 190 −0.210918777 −1.040860630.02614862 3.362615492 191 0.715897301 0.666316436 −0.417195380.400723176 192 0.65612864 1.231196814 0.75462061 1.514581532 193−0.394884432 1.129269425 −0.3157071 −0.61478944 194 −2.111794245−0.71010521 0.53077207 0.59302222 195 1.18880856 0.704463775 1.993127771.419709023 196 1.885714606 0.436434665 1.44657532 1.145809063 1972.174580668 0.133070149 0.99814905 0.871658496 198 −0.533922573−2.16213117 0.5812107 −0.92280453 199 1.493919434 1.45125612 1.951413714.403441058 201 −0.005520296 −0.83362523 0.65480762 −0.38894276 2040.732981164 −0.97494758 −0.91192246 −1.00034323 205 0.991838899−0.60053505 −0.49983634 0.674468753 206 2.147983695 1.2913519581.64553247 1.626455601 208 −0.386224123 −0.24799559 1.19406353−1.61243489 209 1.447075297 0.122626462 1.08021156 0.473154634 210−0.386224123 −0.24799559 1.19406353 −1.61243489 211 2.1861184671.873949371 0.64852028 −0.59205851 212 1.367811201 1.689658923 1.80173762.525531645 213 0.925016223 0.875610609 0.31462609 0.847028648 214−0.239873321 1.808823425 −0.36105512 −0.07650286 215 2.2642750881.360001278 3.25759951 2.147928282 218 −0.509585598 −0.934286431.63030386 −0.79436377 221 1.876297063 0.026873469 0.454427581.538486988 227 5.317676982 2.824566654 1.73360625 3.103310061 2283.323728685 1.554268023 1.8883835 0.957527434 229 3.2189501751.464118271 2.47512497 1.214429025 230 5.242356467 3.4822067153.50441556 1.614847073 230 5.242356467 3.482206715 3.504415561.614847073 231 2.710087358 1.517756148 0.35088855 0.603171932 2312.710087358 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974 0.130904221 1.882440008 1.85101055 0.112524893 976−0.236681385 −0.09745533 0.1779313 2.08923366 977 0.9044026120.936956925 0.87731788 0.102346515 978 2.201759817 2.123549573 3.78816072.358768953 980 1.784266982 1.845281076 3.42873622 −0.31098233 981−0.225023329 0.087962898 −0.29053012 0.514272787 982 −0.231175318−0.0159671 1.27391892 1.090487158 983 0.889215441 0.24321159 0.068776290.816247177 985 1.864634345 0.133647536 1.29803755 1.951226654 9860.511450274 −2.33512445 −0.56246315 −0.42184152 987 0.8472608130.368638185 0.4114346 0.219336109 988 1.596170102 1.592158381 0.300523570.283467897 993 −3.549941097 −2.6847861 −0.17502622 1.41034664 9940.445802042 0.899738574 0.61059602 0.323194673 995 0.9494987240.357111159 0.28371155 −0.14156488 998 2.197271885 1.5788718260.90563334 1.056619658 998 2.197271885 1.578871826 0.905633341.056619658 1000 1.456120673 0.626173572 0.07683183 −0.43324035 1001−0.440378333 0.918089245 0.03050609 −1.62235977 1002 0.8199290660.459101825 −0.09227583 0.324342063 1003 1.64412453 −0.093433990.70197344 3.710273595 1004 0.796928207 0.459954079 −0.885386160.152000937 1005 0.044923203 −0.19994963 0.60082875 0.258347835 1006−0.320452673 −0.33232662 −0.52315783 1.406273663 1007 4.0402911333.474551355 3.57146797 3.565985043 1008 0.764519082 0.9176351022.88258762 2.319622474 1009 −0.071112206 0.539362906 2.980487320.580423329 1010 −0.689737481 0.547928768 1.98805626 −0.76653376 10110.343668917 0.931501008 −0.05483722 0.395369857 1012 1.9267131310.124849138 −0.09654906 1.126499382 1016 0.124247716 0.1931027120.39003599 1.737670628 1017 0.131224136 0.21510779 −1.709963460.964902175 1018 0.499624069 0.962843507 0.77617619 −1.15296947 10190.813491983 0.322635656 0.02800396 0.599500927 1020 0.7154681141.015469049 1.45994989 0.352548581 1021 −1.176339404 1.539767848−0.14427147 1.389902738 1022 1.364966718 1.690570939 2.059141942.364375484 1023 2.154641091 0.800066339 0.85365652 0.965810338 10242.302280068 1.252164308 1.73414439 1.549538352 1025 1.8783315151.287303121 0.11530502 1.132065786 1026 2.97722987 2.0964419653.87172868 0.550274831 1027 2.474381478 1.950326182 3.818618671.366897355 1028 1.778414353 3.114931059 4.47690731 6.054314034 10293.672910795 2.760483725 3.26915034 3.042677588 1030 −0.604959715−2.13584086 0.8687855 0.024144016 1031 2.012732245 2.2938571610.54405555 1.261882121 1032 −1.086688867 0.953083194 2.921770540.876865185 1033 1.617520676 1.008017006 2.21183536 −0.1288484 10352.506372295 3.419954592 4.58206882 4.134341651 1036 −0.675805062−0.15357004 0.94597719 3.966016669 1037 −0.275092569 −0.67687665−0.52763797 1.489972106 1038 2.753559643 3.81185814 2.713447342.243351472 1039 0.65087433 0.026885305 −0.0153558 0.011870127 10400.141526548 −1.65455278 0.50170705 −1.90794 1041 0.458680435 −0.69730218−0.48806249 0.586073092 1042 −0.513264812 −0.22001961 0.363395191.03208599 1043 −1.497887014 −1.76116109 −0.76634926 1.137002742 10452.863652137 1.96790869 0.43661485 −0.44756897 1046 0.9811942481.73892162 2.21166953 2.738129365 1047 0.981194248 1.73892162 2.211669532.738129365 1051 0.70261974 −0.22197386 0.19710806 −2.37196477 10520.662126832 0.741436531 0.61672724 0.289359903 1053 0.87463644−0.19717783 1.2664131 −0.4187507 1054 0.284558077 −1.46754925−0.03124571 0.587227244 1055 0.885837831 −0.91907796 −0.45817355−1.1936897 1057 0.790964847 1.387925398 −0.18370692 1.302393792 1058−1.052897931 −0.85226912 0.90324527 −1.09684959 1059 −0.871565421−0.17856476 1.51267137 −1.52734367 1060 3.311161199 3.0747839212.10199297 1.822541682 1061 −0.655128061 0.497032417 0.92381279−0.56348341 1062 −0.443129049 0.96200606 1.51641349 −0.22974864 10631.385675542 0.738759296 1.1677069 0.501211562 1064 1.670680003−0.20756775 −0.73755051 −0.84924056 1065 1.43532227 1.656262941−1.09448841 1.674272267 1066 1.670680003 1.284791101 0.14864516−0.84985664 1067 2.237616041 0.345329863 −0.60597063 −0.71581056 1069−0.24632881 −0.23975349 −0.01449288 0.574861147 1070 1.6706800030.070165381 −0.64700996 −0.85055617 1071 −1.02687397 −0.362442730.13010074 0.535909448 1072 1.670680003 1.94609957 0.19633838 1.148257641073 2.237616041 1.438074134 0.31117554 −0.71786492 1074 −0.1926329110.142411101 0.79310676 0.125548041 1075 0.909356011 0.3685978871.03689838 1.001198751 1076 0.812238101 0.195908668 0.215646640.219336109 1077 0.325255266 1.131242708 −2.79377204 −0.62848261 10780.325255266 1.131242708 −2.79377204 −0.62848261 1079 0.85330799−0.6855194 −0.90046979 −0.46415796 1081 −0.131519393 0.7318360140.81604919 −1.29993979 1082 0.744770665 0.155243763 −1.80299191.023503542 1083 1.415726941 0.086297223 3.43559555 −0.12964168 10840.161304111 0.66712144 0.58401752 0.373809692 1085 −0.72863532−0.2873027 2.21251376 3.003873022 1088 −1.1773616 −0.23258175 0.405291950.994988969 1089 2.769817302 1.661618789 3.97585272 1.059236597 10903.052627325 0.420821685 −0.57080756 1.751222205 1091 −3.379896722−3.71174986 2.53586709 0.644702886 1093 0.72304265 1.6670114762.53982093 2.7903213 1095 0.744219765 1.372184572 0.15852396 1.1260534421097 4.407270402 2.670641491 5.02636153 5.361271976 1098 −1.85804837−2.59071226 −0.46522239 0.655734646 1099 0.745797788 −0.205473784.27836342 4.646390386 1102 2.068748434 −0.24299896 0.07214682−1.11758276 1104 1.018876287 0.025163067 −0.1106021 0.838914654 11052.387326861 3.865456674 2.2251199 0.728667998 1107 2.3525820592.595496601 3.20492728 2.844590737 1110 0.302703712 0.599942142−0.25637571 −0.03195517 1111 0.750930333 0.656784751 1.683264130.329846578 1112 −0.205527848 0.287622624 −0.00340777 0.59203719 11150.999825037 0.662221152 0.43571192 0.342558518 1116 0.8733812631.544324176 0.13703728 −0.38172701 1117 −0.682983903 1.7982043022.42110319 −0.39173951 1118 0.069769623 0.496895599 0.67857133−0.14954441 1119 −0.671908804 −0.65984824 0.5238174 −0.85314111 11200.953790113 1.106552668 3.00006904 1.585038764 1121 −1.1846309732.476138312 4.80971952 2.450646806 1122 −1.02687397 −0.362442730.13010074 0.535909448 1125 0.387315524 −0.36101406 1.14153708−0.75303953 1126 1.021783831 −0.0070257 −0.14327539 3.954381426 11270.990592079 0.305612583 0.14155512 −0.29526854 1128 0.9905920790.305612583 0.14155512 −0.29526854 1129 3.18966648 3.2843629874.49398568 3.950809104 1131 1.650621055 1.545704806 2.375350811.259373143 1133 −1.519747805 −0.60804324 0.02746106 0.590708892 11340.815942067 −0.16126019 −0.54117238 0.613093526 1135 0.6269733851.998305877 2.61706075 1.570404253 1136 2.812199484 1.3531981462.05618426 1.869204406 1137 2.208307057 1.387136198 3.215213742.069795393 1138 1.670680003 1.316442078 0.14822999 −0.46985154 11391.408517438 0.890457374 1.24524408 0.685687797 1140 2.7658609522.525539595 4.12464228 3.833744077 1141 −0.484394663 0.677713073−0.22783646 −0.37267608 1142 2.54335679 4.298105601 3.362342382.684404542 1143 4.204367611 3.062126931 3.4234313 2.072899554 11442.479165229 3.226545885 4.65897152 4.952127235 1145 2.4791589213.226545885 4.65897152 4.952127235 1146 0.774334025 1.0758007741.06893156 1.011113116 1147 0.844648531 1.21935371 2.591385950.805938034 1148 2.906236436 1.550674121 3.56959167 2.832126896 11492.837627443 3.707154326 4.53384262 2.625871865

Solid Consumer Products and Methods

A product, preferably said product is a powder, granule, flake, bar orbead, said product comprising:

-   -   a) a sum total from about 0.001% to about 20%, preferably from        about 0.005% to about 10%, more preferably from about 0.025% to        about 1%, most preferably from about 0.05% to about 0.5% of 1 to        about 30 malodor reduction materials, preferably 1 to about 25        malodor reduction materials, more preferably 1 to about 15        malodor reduction materials and most preferably about 1 to about        10 malodor reduction materials having a Blocker Index of less        than 3, more preferable less than about 2.5 even more preferably        less than about 2 and still more preferably less than about 1        and most preferably 0 or a Blocker Index average of 3 to about        0.001; preferably at least a portion of said malodor reduction        materials are encapsulated;    -   b) a carrier that is a solid at 25° C., preferably said solid        carrier is selected from the group consisting of clays, sugars,        salts, silicates, zeolites, citric acid, maleic acid, succinic        acid, benzoic acid, urea and polyethylene oxide and mixtures        thereof; preferably said carriers is present at a level of:        -   (i) from about 20% to about 95%, more preferably about 30%            to about 90%, even more preferably about 45% to about 90%,            and most preferably about 60% to about 88%; or        -   (ii) from about 1% to about 60%, more preferably about 2% to            about 50%, even more preferably about 3% to about 45% and            most preferably, about 4% to about 40%; and    -   c) optionally, 0.5% to about 50% of an enzyme stable polymer,        preferably said enzyme stable polymer is selected from the group        consisting of polyacrylate polymers, polyamine polymer,        acrylate/maleate copolymer, a polysaccharide, and mixtures        thereof, preferably said polysaccharide is selected from the        group consisting of carboxy methyl cellulose, cationic hydroxy        ethyl cellulose and mixtures thereof, is disclosed.

In one aspect of said product, said malodor reduction materials have aFragrance Fidelity Index of from about Fragrance Fidelity Index of lessthan 3, more preferable less than about 2.5 even more preferably lessthan about 2 and still more preferably less than about 1 and mostpreferably 0 or a Fragrance Fidelity Index average of 3 to about 0.001.

In one aspect of said product, said product comprises a perfume.

In one aspect of said product, said composition comprising a weightratio of parts of malodor reduction composition to perfume of from about1:20,000 to about 3000:1, preferably from about 1:10,000 to about1,000:1, more preferably 5,000:1 to about 500:1, most preferably fromabout 1:15 to about 1:1.

In one aspect of said product, said product comprises one or moremalodor reduction materials having a log P greater than 3, preferablygreater than 3 but less than 8, preferably said one or more malodorreduction materials are selected from the group consisting of Table 1materials 1; 2; 3; 7; 9; 10; 11; 13; 14; 18; 21; 22; 23; 25; 28; 29; 30;31; 32; 33; 35; 36; 38; 39; 47; 48; 49; 50; 52; 57; 62; 63; 64; 67; 68;69; 71; 74; 75; 76; 77; 78; 79; 80; 83; 85; 91; 92; 93; 100; 101; 102;103; 104; 105; 109; 114; 119; 120; 122; 123; 128; 134; 135; 137; 140;142; 145; 148; 149; 152; 153; 158; 159; 161; 162; 174; 175; 176; 177;178; 182; 183; 184; 185; 186; 189; 192; 195; 196; 197; 206; 208; 209;210; 211; 212; 215; 221; 227; 228; 229; 230; 231; 233; 234; 238; 242;243; 244; 246; 252; 253; 260; 261; 263; 267; 269; 271; 274; 276; 277;280; 285; 289; 290; 292; 293; 294; 295; 296; 300; 301; 303; 307; 316;317; 318; 322; 324; 325; 328; 329; 330; 331; 333; 334; 335; 336; 338;339; 342; 343; 344; 349; 352; 356; 358; 359; 360; 361; 362; 363; 364;368; 369; 370; 371; 372; 378; 381; 385; 386; 388; 390; 391; 397; 398;413; 414; 416; 418; 421; 424; 426; 428; 429; 432; 441; 444; 449; 453;457; 459; 461; 462; 463; 465; 466; 467; 468; 470; 471; 473; 475; 478;479; 480; 482; 484; 486; 487; 488; 497; 498; 501; 502; 503; 505; 519;520; 521; 524; 529; 532; 534; 537; 541; 544; 548; 550; 552; 558; 559;560; 561; 562; 563; 565; 566; 567; 568; 569; 570; 571; 572; 573; 574;577; 578; 582; 584; 589; 591; 592; 594; 599; 600; 601; 603; 604; 606;607; 608; 609; 610; 611; 613; 614; 615; 616; 618; 620; 621; 624; 625;626; 628; 631; 632; 633; 635; 644; 650; 653; 659; 660; 661; 663; 671;673; 674; 675; 676; 677; 678; 679; 680; 681; 684; 686; 691; 692; 693;694; 696; 697; 698; 700; 702; 704; 706; 707; 708; 709; 710; 711; 712;713; 714; 715; 716; 717; 718; 719; 720; 721; 722; 723; 724; 725; 726;727; 731; 741; 746; 750; 752; 754; 757; 758; 763; 766; 769; 770; 771;774; 775; 776; 778; 781; 782; 788; 791; 800; 802; 804; 806; 814; 821;826; 827; 828; 831; 837; 839; 840; 849; 850; 852; 856; 866; 868; 869;870; 871; 872; 873; 876; 877; 878; 879; 881; 884; 885; 886; 890; 892;893; 894; 905; 908; 912; 913; 914; 916; 919; 920; 922; 925; 926; 927;930; 933; 939; 941; 942; 943; 945; 947; 948; 950; 951; 953; 954; 959;965; 967; 973; 978; 985; 988; 998; 1000; 1003; 1006; 1007; 1008; 1009;1010; 1016; 1022; 1023; 1024; 1025; 1028; 1029; 1031; 1032; 1033; 1035;1038; 1045; 1046; 1047; 1053; 1057; 1060; 1062; 1063; 1065; 1067; 1070;1073; 1075; 1077; 1078; 1082; 1089; 1090; 1093; 1095; 1097; 1099; 1102;1104; 1105; 1107; 1116; 1120; 1121; 1126; 1129; 1131; 1135; 1136; 1137;1138; 1140; 1142; 1143; 1144; 1145; 1147; 1148; 1149; Table 2 materials2; 23; 54/28; 227; 230; 246; 248; 343; 359; 565; 631; 659; 674; 678;679; 715; 758; 1028; 1097; Table 3 materials 1; 9; 12; 13; 19; 20; 21;24; 25; 27; 32; 38; 54; 55; 59; 64; 68; 71; 72; 79; 81; 83; 85; 100;105; 109; 111; 114; 119; 133; 134; 135; 137; 140; 142; 147; 148; 150;151; 152; 153; 154; 157; 159; 162; 178; 181; 189; 191; 192; 195; 197;204; 211; 228; 231; 233; 234; 237; 238; 242; 246; 252; 264; 270; 273;275; 277; 283; 285; 289; 290; 292; 293; 295; 300; 301; 302; 306; 308;310; 312; 319; 322; 325; 331; 333; 334; 336; 338; 339; 344; 346; 354;355; 356; 358; 361; 362; 363; 370; 371; 372; 378; 381; 385; 387; 388;390; 412; 413; 418; 420; 428; 429; 432; 437; 438; 444; 447; 448; 454;455; 457; 461; 465; 467; 472; 477; 478; 479; 480; 481; 482; 495; 496;497; 502; 503; 504; 509; 510; 512; 515; 517; 518; 522; 525; 529; 535;536; 537; 540; 541; 544; 550; 557; 558; 559; 560; 561; 568; 571; 572;575; 589; 54/15; 594; 599; 600; 602; 604; 609; 619; 620; 625; 626; 633;641; 644; 645; 650; 653; 662; 667; 672; 673; 675; 676; 681; 686; 687;693; 697; 698; 700; 703; 704; 706; 707; 716; 717; 718; 722; 725; 744;745; 746; 757; 769; 771; 779; 782; 799; 806; 819; 820; 827; 828; 836;838; 839; 847; 850; 875; 878; 879; 880; 881; 888; 889; 890; 891; 893;899; 900; 901; 903; 909; 912; 914; 920; 922; 930; 939; 940; 941; 945;947; 948; 953; 954; 958; 959; 960; 965; 967; 971; 986; 987; 994; 995;998; 1000; 1001; 1003; 1005; 1008; 1009; 1010; 1011; 1017; 1018; 1023;1031; 1032; 1046; 1047; 1051; 1052; 1053; 1054; 1055; 1057; 1058; 1061;1062; 1063; 1074; 1075; 1076; 1082; 1088; 1093; 1095; 1099; 1102; 1104;1105; 1115; 1116; 1120; 1127; 1128; 1134; 1135; 1141; 1147; 1148, 1149,and mixtures thereof; preferably said malodor reduction materials areselected from the group consisting of Table 1 materials 1; 2; 3; 7; 9;10; 11; 13; 14; 18; 21; 22; 23; 25; 28; 29; 30; 31; 32; 33; 35; 36; 38;39; 47; 48; 49; 50; 52; 57; 62; 63; 64; 67; 68; 69; 71; 74; 75; 76; 77;78; 79; 80; 83; 85; 91; 92; 93; 100; 101; 102; 103; 104; 105; 109; 114;119; 120; 122; 123; 128; 134; 135; 137; 140; 142; 145; 148; 149; 152;153; 158; 159; 161; 162; 174; 175; 176; 177; 178; 182; 183; 184; 185;186; 189; 192; 195; 196; 197; 206; 208; 209; 210; 211; 212; 215; 221;227; 228; 229; 230; 231; 233; 234; 238; 242; 243; 244; 246; 252; 253;260; 261; 263; 267; 269; 271; 274; 276; 277; 280; 285; 289; 290; 292;293; 294; 295; 296; 300; 301; 303; 307; 316; 317; 318; 322; 324; 325;328; 329; 330; 331; 333; 334; 335; 336; 338; 339; 342; 343; 344; 349;352; 356; 358; 359; 360; 361; 362; 363; 364; 368; 369; 370; 371; 372;378; 381; 385; 386; 388; 390; 391; 397; 398; 413; 414; 416; 418; 421;424; 426; 428; 429; 432; 441; 444; 449; 453; 457; 459; 461; 462; 463;465; 466; 467; 468; 470; 471; 473; 475; 478; 479; 480; 482; 484; 486;487; 488; 497; 498; 501; 502; 503; 505; 519; 520; 521; 524; 529; 532;534; 537; 541; 544; 548; 550; 552; 558; 559; 560; 561; 562; 563; 565;566; 567; 568; 569; 570; 571; 572; 573; 574; 577; 578; 582; 584; 589;591; 592; 594; 599; 600; 601; 603; 604; 606; 607; 608; 609; 610; 611;613; 614; 615; 616; 618; 620; 621; 624; 625; 626; 628; 631; 632; 633;635; 644; 650; 653; 659; 660; 661; 663; 671; 673; 674; 675; 676; 677;678; 679; 680; 681; 684; 686; 691; 692; 693; 694; 696; 697; 698; 700;702; 704; 706; 707; 708; 709; 710; 711; 712; 713; 714; 715; 716; 717;718; 719; 720; 721; 722; 723; 724; 725; 726; 727; 731; 741; 746; 750;752; 754; 757; 758; 763; 766; 769; 770; 771; 774; 775; 776; 778; 781;782; 788; 791; 800; 802; 804; 806; 814; 821; 826; 827; 828; 831; 837;839; 840; 849; 850; 852; 856; 866; 868; 869; 870; 871; 872; 873; 876;877; 878; 879; 881; 884; 885; 886; 890; 892; 893; 894; 905; 908; 912;913; 914; 916; 919; 920; 922; 925; 926; 927; 930; 933; 939; 941; 942;943; 945; 947; 948; 950; 951; 953; 954; 959; 965; 967; 973; 978; 985;988; 998; 1000; 1003; 1006; 1007; 1008; 1009; 1010; 1016; 1022; 1023;1024; 1025; 1028; 1029; 1031; 1032; 1033; 1035; 1038; 1045; 1046; 1047;1053; 1057; 1060; 1062; 1063; 1065; 1067; 1070; 1073; 1075; 1077; 1078;1082; 1089; 1090; 1093; 1095; 1097; 1099; 1102; 1104; 1105; 1107; 1116;1120; 1121; 1126; 1129; 1131; 1135; 1136; 1137; 1138; 1140; 1142; 1143;1144; 1145; 1147; 1148; 1149; Table 2 materials 2; 23; 185; 227; 230;246; 248; 343; 359; 565; 631; 659; 674; 678; 679; 715; 758; 1028; 1097and mixtures thereof; more preferably said malodor reduction materialsare selected from the group consisting of Table 4 materials 7; 14; 39;48; 183; 206; 212; 215; 229; 260; 55/21; 329; 335; 360; 441; 484; 487;488; 501; 566; 567; 569; 570; 573; 574; 603; 616; 621; 624; 632; 663;680; 684; 694; 696; 708; 712; 714; 726; 750; 775; 776; 788; 804; 872;919; 927; 933; 978; 1007; 1022; 1024; 1029; 1035; 1038; 1060; 1089;1107; 1129; 1131; 1136; 1137; 1140; 1142; 1143; 1144; 1145; 1148; 1149Table 5 material 248 and mixtures thereof, most preferably said materialis selected from the group consisting of Table 4 materials 261; 680;788; 1129, 1148, 1149 and mixtures thereof. All of the aforementionedmaterials have a log P that is equal to or greater than 3, thus theydeposit through the wash especially well. The more preferred and mostpreferred of the aforementioned material are particularly preferred asthey are effective at counteracting all of the key malodors.

In one aspect of said product, said malodor reduction materials are notselected from the group consisting of Table 1-3 malodor reductionmaterials 302; 288; 50; 157; 1017; 888; 64; 1054; 832; 375; 390; 745;504; 505; 140; 1012; 498; 362; 103; 356; 1074; 908; 1127; 475; 918; 687;611; 317; 9; 141; 550; 602; 913; 1005; 521; 10; 215; 370; 335; 378;1121; 360; 565; 1136; 1129; 655; 369; 1065; 914; 757; 601; 478; 889;891; 358; 973; 162; 554; 522; 312; 125; 26; 418; 92; 586; 1026; 218; 31;828; 871; 829; 1066; 287; 269; 769; 701; 1118; 70; 946; 142; 109; 108 ormixtures thereof.

In one aspect of said product, said product comprising an additionalmaterial that is an adjunct ingredient selected from the groupconsisting of surfactants, builders, chelating agents, dye transferinhibiting agents, dispersants, enzymes, and enzyme stabilizers,catalytic materials, bleach activators, a fabric softener active,hydrogen peroxide, sources of hydrogen peroxide, preformed peracids,polymeric dispersing agents, clay soil removal/anti-redeposition agents,brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfumedelivery systems, structure elasticizing agents, carriers, structurants,hydrotropes, processing aids, solvents, pigments and mixtures thereof.

Method of Use

The compositions of the present invention may be used in anyconventional manner. In short, they may be used in the same manner asproducts that are designed and produced by conventional methods andprocesses. For example, compositions of the present invention can beused to treat a situs inter alia a surface or fabric. Typically at leasta portion of the situs is contacted with an aspect of Applicants'composition, in neat form or diluted in a wash liquor, and then thesitus is optionally washed and/or rinsed. For purposes of the presentinvention, washing includes but is not limited to, scrubbing, andmechanical agitation. The fabric may comprise any fabric capable ofbeing laundered in normal consumer use conditions. When the wash solventis water, the water temperature typically ranges from about 5° C. toabout 90° C. and, when the situs comprises a fabric, the water to fabricmass ratio is typically from about 1:1 to about 100:1.

The compositions of the present invention may be used as liquid fabricenhancers wherein they are applied to a fabric and the fabric is thendried via line drying and/or drying the an automatic dryer.

A method of controlling malodors comprising: contacting a situscomprising a malodor and/or a situs that will become malodorous with aproduct selected from the group consisting of the products describedherein and mixtures thereof, is disclosed.

In one aspect, said situs comprises a fabric and said contacting stepcomprises contacting said fabric with a sufficient amount of Applicants'solid consumer products to provide said fabric with a level of malodorreduction material at least 0.001 mg of malodor reduction material/kg offabric, preferably from about 0.001 mg of malodor reduction material/kgof fabric to about 30 mg of malodor reduction material/kg of fabric,more preferably from about 0.1 mg of malodor reduction material/kg offabric to about 20 mg of malodor reduction material/kg of fabric, mostpreferably from about 0.2 of malodor reduction material/kg of fabric toabout 10 mg of malodor reduction material/kg of fabric of said sum ofmalodor reduction materials.

Adjunct Materials

While not essential for the purposes of the present invention, thenon-limiting list of adjuncts illustrated hereinafter are suitable foruse in the instant compositions and may be desirably incorporated incertain aspects of the invention, for example to assist or enhancecleaning performance, for treatment of the substrate to be cleaned, orto modify the aesthetics of the composition as is the case withperfumes, colorants, dyes or the like. The precise nature of theseadditional components, and levels of incorporation thereof, will dependon the physical form of the composition and the nature of the fabrictreatment operation for which it is to be used. Suitable adjunctmaterials include, but are not limited to, surfactants, builders,chelating agents, dye transfer inhibiting agents, dispersants, enzymes,and enzyme stabilizers, catalytic materials, bleach activators, hydrogenperoxide, sources of hydrogen peroxide, preformed peracids, polymericdispersing agents, clay soil removal/anti-redeposition agents,brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfumedelivery systems, structure elasticizing agents, carriers, structurants,hydrotropes, processing aids, solvents, pigments and/or fabric softeneractives.

As stated, the adjunct ingredients are not essential to Applicants'compositions. Thus, certain aspects of Applicants' compositions do notcontain one or more of the following adjuncts materials: surfactants,builders, chelating agents, dye transfer inhibiting agents, dispersants,enzymes, and enzyme stabilizers, catalytic materials, bleach activators,hydrogen peroxide, sources of hydrogen peroxide, preformed peracids,polymeric dispersing agents, clay soil removal/anti-redeposition agents,brighteners, suds suppressors, dyes, hueing dyes, perfumes, perfumedelivery systems structure elasticizing agents, carriers, hydrotropes,processing aids, solvents, pigments and/or fabric softener actives.However, when one or more adjuncts are present, such one or moreadjuncts may be present as detailed below.

Hueing Dye—

The liquid laundry detergent composition may comprise a hueing dye. Thehueing dyes employed in the present laundry care compositions maycomprise polymeric or non-polymeric dyes, organic or inorganic pigments,or mixtures thereof. Preferably the hueing dye comprises a polymericdye, comprising a chromophore constituent and a polymeric constituent.The chromophore constituent is characterized in that it absorbs light inthe wavelength range of blue, red, violet, purple, or combinationsthereof upon exposure to light. In one aspect, the chromophoreconstituent exhibits an absorbance spectrum maximum from about 520nanometers to about 640 nanometers in water and/or methanol, and inanother aspect, from about 560 nanometers to about 610 nanometers inwater and/or methanol.

Although any suitable chromophore may be used, the dye chromophore ispreferably selected from benzodifuranes, methine, triphenylmethanes,napthalimides, pyrazole, napthoquinone, anthraquinone, azo, oxazine,azine, xanthene, triphenodioxazine and phthalocyanine dye chromophores.Mono and di-azo dye chromophores are may be preferred.

The hueing dye may comprise a dye polymer comprising a chromophorecovalently bound to one or more of at least three consecutive repeatunits. It should be understood that the repeat units themselves do notneed to comprise a chromophore. The dye polymer may comprise at least 5,or at least 10, or even at least 20 consecutive repeat units.

The repeat unit can be derived from an organic ester such as phenyldicarboxylate in combination with an oxyalkyleneoxy and apolyoxyalkyleneoxy. Repeat units can be derived from alkenes, epoxides,aziridine, carbohydrate including the units that comprise modifiedcelluloses such as hydroxyalkylcellulose; hydroxypropyl cellulose;hydroxypropyl methylcellulose; hydroxybutyl cellulose; and, hydroxybutylmethylcellulose or mixtures thereof. The repeat units may be derivedfrom alkenes, or epoxides or mixtures thereof. The repeat units may beC₂-C₄ alkyleneoxy groups, sometimes called alkoxy groups, preferablyderived from C₂-C₄ alkylene oxide. The repeat units may be C₂-C₄ alkoxygroups, preferably ethoxy groups.

For the purposes of the present invention, the at least threeconsecutive repeat units form a polymeric constituent. The polymericconstituent may be covalently bound to the chromophore group, directlyor indirectly via a linking group. Examples of suitable polymericconstituents include polyoxyalkylene chains having multiple repeatingunits. In one aspect, the polymeric constituents include polyoxyalkylenechains having from 2 to about 30 repeating units, from 2 to about 20repeating units, from 2 to about 10 repeating units or even from about 3or 4 to about 6 repeating units. Non-limiting examples ofpolyoxyalkylene chains include ethylene oxide, propylene oxide, glycidoloxide, butylene oxide and mixtures thereof.

Surfactants—

The compositions according to the present invention may comprise asurfactant or surfactant system wherein the surfactant can be selectedfrom nonionic surfactants, anionic surfactants, cationic surfactants,ampholytic surfactants, zwitterionic surfactants, semi-polar nonionicsurfactants and mixtures thereof.

The surfactant is typically present at a level of from about 0.1% toabout 60%, from about 1% to about 50% or even from about 5% to about 40%by weight of the subject composition.

Chelating Agents—

The compositions herein may contain a chelating agent. Suitablechelating agents include copper, iron and/or manganese chelating agentsand mixtures thereof. When a chelating agent is used, the compositionmay comprise from about 0.1% to about 15% or even from about 3.0% toabout 10% chelating agent by weight of the subject composition.

Dye Transfer Inhibiting Agents—

The compositions of the present invention may also include one or moredye transfer inhibiting agents. Suitable polymeric dye transferinhibiting agents include, but are not limited to, polyvinylpyrrolidonepolymers, polyamine N-oxide polymers, copolymers of N-vinylpyrrolidoneand N-vinylimidazole, polyvinyloxazolidones and polyvinylimidazoles ormixtures thereof.

When present in a subject composition, the dye transfer inhibitingagents may be present at levels from about 0.0001% to about 10%, fromabout 0.01% to about 5% or even from about 0.1% to about 3% by weight ofthe composition.

Dispersants—

The compositions of the present invention can also contain dispersants.Suitable water-soluble organic materials include the homo- orco-polymeric acids or their salts, in which the polycarboxylic acidcomprises at least two carboxyl radicals separated from each other bynot more than two carbon atoms.

Perfumes—

The dispersed phase may comprise a perfume that may include materialsselected from the group consisting of perfumes such as3-(4-t-butylphenyl)-2-methyl propanal, 3-(4-t-butylphenyl)-propanal,3-(4-isopropylphenyl)-2-methylpropanal,methylenedioxyphenyl)-2-methylpropanal, and 2,6-dimethyl-5-heptenal,alpha-damascone, beta-damascone, delta-damascone, beta-damascenone,6,7-dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone,methyl-7,3-dihydro-2H-1,5-benzodioxepine-3-one,2-[2-(4-methyl-3-cyclohexenyl-1-yl)propyl]cyclopentan-2-one,2-sec-butylcyclohexanone, and beta-dihydro ionone, linalool,ethyllinalool, tetrahydrolinalool, and dihydromyrcenol.

Perfume Delivery Technologies—

The compositions of the present invention may comprise one or moreperfume delivery technologies that stabilize and enhance the depositionand release of perfume ingredients from treated substrate. Such perfumedelivery technologies can also be used to increase the longevity ofperfume release from the treated substrate. Perfume deliverytechnologies, methods of making certain perfume delivery technologiesand the uses of such perfume delivery technologies are disclosed in US2007/0275866 A1.

In one aspect, the compositions of the present invention may comprisefrom about 0.001% to about 20%, or from about 0.01% to about 10%, orfrom about 0.05% to about 5%, or even from about 0.1% to about 0.5% byweight of the perfume delivery technology. In one aspect, said perfumedelivery technologies may be selected from the group consisting of:perfume microcapsules, pro-perfumes, polymer particles, functionalizedsilicones, polymer assisted delivery, molecule assisted delivery, fiberassisted delivery, amine assisted delivery, cyclodextrins, starchencapsulated accord, zeolite and inorganic carrier, and mixturesthereof:

In one aspect, said perfume delivery technology may comprise perfumemicrocapsules formed by at least partially surrounding a benefit agentwith a wall material. Said benefit agent may include materials selectedfrom the group consisting of perfumes such as3-(4-t-butylphenyl)-2-methyl propanal, 3-(4-t-butylphenyl)-propanal,3-(4-isopropylphenyl)-2-methylprop anal,3-(3,4-methylenedioxyphenyl)-2-methylpropanal, and2,6-dimethyl-5-heptenal, alpha-damascone, beta-damascone,delta-damascone, beta-damascenone,6,7-dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone,methyl-7,3-dihydro-2H-1,5-benzodioxepine-3-one,2-[2-(4-methyl-3-cyclohexenyl-1-yl)propyl]cyclopentan-2-one,2-sec-butylcyclohexanone, and beta-dihydro ionone, linalool,ethyllinalool, tetrahydrolinalool, and dihydromyrcenol. Suitable perfumematerials can be obtained from Givaudan Corp. of Mount Olive, N.J., USA,International Flavors & Fragrances Corp. of South Brunswick, N.J., USA,or Quest Corp. of Naarden, Netherlands. In one aspect, the microcapsulewall material may comprise: melamine, polyacrylamide, silicones, silica,polystyrene, polyurea, polyurethanes, polyacrylate based materials,gelatin, styrene malic anhydride, polyamides, and mixtures thereof. Inone aspect, said melamine wall material may comprise melaminecrosslinked with formaldehyde, melamine-dimethoxyethanol crosslinkedwith formaldehyde, and mixtures thereof. In one aspect, said polystyrenewall material may comprise polyestyrene cross-linked withdivinylbenzene. In one aspect, said polyurea wall material may compriseurea crosslinked with formaldehyde, urea crosslinked withgluteraldehyde, and mixtures thereof. In one aspect, said polyacrylatebased materials may comprise polyacrylate formed frommethylmethacrylate/dimethylaminomethyl methacrylate, polyacrylate formedfrom amine acrylate and/or methacrylate and strong acid, polyacrylateformed from carboxylic acid acrylate and/or methacrylate monomer andstrong base, polyacrylate formed from an amine acrylate and/ormethacrylate monomer and a carboxylic acid acrylate and/or carboxylicacid methacrylate monomer, and mixtures thereof. In one aspect, theperfume microcapsule may be coated with a deposition aid, a cationicpolymer, a non-ionic polymer, an anionic polymer, or mixtures thereof.Suitable polymers may be selected from the group consisting of:polyvinylformaldehyde, partially hydroxylated polyvinylformaldehyde,polyvinylamine, polyethyleneimine, ethoxylated polyethyleneimine,polyvinylalcohol, polyacrylates, and combinations thereof. In oneaspect, the microcapsule may be a perfume microcapsule. In one aspect,one or more types of microcapsules, for example two microcapsules typeshaving different benefit agents may be used.

In one aspect, said perfume delivery technology may comprise an aminereaction product (ARP) or a thio reaction product. One may also use“reactive” polymeric amines and or polymeric thiols in which the amineand/or thiol functionality is pre-reacted with one or more PRMs to forma reaction product. Typically the reactive amines are primary and/orsecondary amines, and may be part of a polymer or a monomer(non-polymer). Such ARPs may also be mixed with additional PRMs toprovide benefits of polymer-assisted delivery and/or amine-assisteddelivery. Nonlimiting examples of polymeric amines include polymersbased on polyalkylimines, such as polyethyleneimine (PEI), orpolyvinylamine (PVAm). Nonlimiting examples of monomeric (non-polymeric)amines include hydroxyl amines, such as 2-aminoethanol and its alkylsubstituted derivatives, and aromatic amines such as anthranilates. TheARPs may be premixed with perfume or added separately in leave-on orrinse-off applications. In another aspect, a material that contains aheteroatom other than nitrogen and/or sulfur, for example oxygen,phosphorus or selenium, may be used as an alternative to aminecompounds. In yet another aspect, the aforementioned alternativecompounds can be used in combination with amine compounds. In yetanother aspect, a single molecule may comprise an amine moiety and oneor more of the alternative heteroatom moieties, for example, thiols,phosphines and selenols. The benefit may include improved delivery ofperfume as well as controlled perfume release. Suitable ARPs as well asmethods of making same can be found in USPA 2005/0003980 A1 and U.S.Pat. No. 6,413,920 B1.

Test Methods

Malodor reduction materials may be separated from mixtures, includingbut not limited to finished products such as consumer products andindentified, by analytical methods that include GC-MS and/or NMR.

Test Method for Determining Saturation Vapour Pressure (VP)

The saturation Vapour Pressure (VP) values are computed for each PRM inthe perfume mixture being tested. The VP of an individual PRM iscalculated using the VP Computational Model, version 14.02 (Linux)available from Advanced Chemistry Development Inc. (ACD/Labs) (Toronto,Canada) to provide the VP value at 25° C. expressed in units of torr.The ACD/Labs' Vapor Pressure model is part of the ACD/Labs model suite.

Test Method for Determining the Logarithm of the Octanol/Water PartitionCoefficient (Log P)

The value of the log of the Octanol/Water Partition Coefficient (log P)is computed for each PRM in the perfume mixture being tested. The log Pof an individual PRM is calculated using the Consensus log PComputational Model, version 14.02 (Linux) available from AdvancedChemistry Development Inc. (ACD/Labs) (Toronto, Canada) to provide theunitless log P value. The ACD/Labs' Consensus log P Computational Modelis part of the ACD/Labs model suite.

Test Method for the Generation of Molecular Descriptors

In order to conduct the calculations involved in the computed-value testmethods described herein, the starting information required includes theidentity, weight percent, and molar percent of each PRM in the perfumebeing tested, as a proportion of that perfume, wherein all PRMs in theperfume composition are included in the calculations. Additionally foreach of those PRMs, the molecular structure, and the values of variouscomputationally-derived molecular descriptors are also required, asdetermined in accordance with the Test Method for the Generation ofMolecular Descriptors described herein.

For each PRM in a perfume mixture or composition, its molecularstructure is used to compute various molecular descriptors. Themolecular structure is determined by the graphic molecular structurerepresentations provided by the Chemical Abstract Service (“CAS”), adivision of the American Chemical Society, Columbus, Ohio, U.S.A. Thesemolecular structures may be obtained from the CAS Chemical RegistrySystem database by looking up the index name or CAS number of each PRM.For PRMs, which at the time of their testing are not yet listed in theCAS Chemical Registry System database, other databases or informationsources may be used to determine their structures. For a PRM which haspotentially more than one isomer present, the molecular descriptorcomputations are conducted using the molecular structure of only one ofthe isomers, which is selected to represent that PRM. The selection ofisomer is determined by the relative amount of extension in themolecular structures of the isomers. Of all the isomers of a given PRM,it is the isomer whose molecular structure that is the most prevalentwhich is the one that is selected to represent that PRM. The structuresfor other potential isomers of that PRM are excluded from thecomputations. The molecular structure of the isomer that is the mostprevalent is paired with the concentration of that PRM, where theconcentration reflects the presence of all the isomers of that PRM thatare present.

A molecule editor or molecular sketching software program, such asChemDraw (CambridgeSoft/PerkinElmer Inc., Waltham, Mass., U.S.A.), isused to duplicate the 2-dimensional molecular structure representingeach PRM. Molecular structures should be represented as neutral species(quaternary nitrogen atoms are allowed) with no disconnected fragments(e.g., single structures with no counter ions). The winMolconn programdescribed below can convert any deprotonated functional groups to theneutral form by adding the appropriate number of hydrogen atoms and willdiscard the counter ion.

For each PRM, the molecular sketching software is used to generate afile which describes the molecular structure of the PRM. The file(s)describing the molecular structures of the PRMs is subsequentlysubmitted to the computer software program winMolconn, version 1.0.1.3(Hall Associates Consulting, Quincy, Mass., U.S.A., www.molconn.com), inorder to derive various molecular descriptors for each PRM. As such, itis the winMolconn software program which dictates the structurenotations and file formats that are acceptable options. These optionsinclude either a MACCS SDF formatted file (i.e., a Structure-Data File);or a Simplified Molecular Input Line Entry Specification (i.e., a SMILESstring structure line notation) which is commonly used within a simpletext file, often with a “.smi” or “.txt” file name extension. The SDFfile represents each molecular structure in the format of a multi-linerecord, while the syntax for a SMILES structure is a single line of textwith no white space. A structure name or identifier can be added to theSMILES string by including it on the same line following the SMILESstring and separated by a space, e.g.: C1=CC═CC═C1 benzene.

The winMolconn software program is used to generate numerous moleculardescriptors for each PRM, which are then output in a table format.Specific molecular descriptors derived by winMolconn are subsequentlyused as inputs (i.e., as variable terms in mathematical equations) for avariety of computer model test methods in order to calculate values suchas: saturation Vapour Pressure (VP); Boiling Point (BP); logarithm ofthe Octanol/Water Partition Coefficient (log P); Odour DetectionThreshold (ODT); Malodour Reduction Value (MORV); and/or UniversalMalodour Reduction Value (Universal MORV) for each PRM. The moleculardescriptor labels used in the models' test method computations are thesame labels reported by the winMolconn program, and their descriptionsand definitions can be found listed in the winMolconn documentation. Thefollowing is a generic description of how to execute the winMolconnsoftware program and generate the required molecular structuredescriptors for each PRM in a composition.

Computing Molecular Structure Descriptors Using winMolconn:

-   -   1) Assemble the molecular structure for one or more perfume        ingredients in the form of a MACCS Structure-Data File, also        called an SDF file, or as a SMILES file.    -   2) Using version 1.0.1.3 of the winMolconn program, running on        an appropriate computer, compute the full complement of        molecular descriptors that are available from the program, using        the SDF or SMILES file described above as input.        -   a. The output of winMolconn is in the form of an ASCII text            file, typically space delimited, containing the structure            identifiers in the first column and respective molecular            descriptors in the remaining columns for each structure in            the input file.    -   3) Parse the text file into columns using a spreadsheet software        program or some other appropriate technique. The molecular        descriptor labels are found on the first row of the resulting        table.    -   4) Find and extract the descriptor columns, identified by the        molecular descriptor label, corresponding to the inputs required        for each model.        -   a. Note that the winMolconn molecular descriptor labels are            case-sensitive.

MORV and Universal MORV Calculation

-   1.) Input Molecular Descriptor values as determined via the method    above into the following four equations:

MORV=−8.5096+2.8597×(dxp9)+1.1253×(knotpv)−0.34484×(e1C2O2)−0.00046231×(idw)+3.3509×(idcbar)+0.11158×(n2pag22)  a)

MORV=−5.2917+2.1741×(dxvp5)−2.6595×(dxvp8)+0.45297×(e1C2C2d)−0.6202×(c1C2O2)+1.3542×(CdCH2)+0.68105×(CaasC)+1.7129×(idcbar)  b)

MORV=−0.0035+0.8028×(SHCsatu)+2.1673×(xvp7)−1.3507×(c1C1C3d)+0.61496×(c1C102)+0.00403×(idc)−0.23286×(nd2).  c)

MORV=−0.9926−0.03882×(SdO)+0.1869×(Ssp3OH)+2.1847×(xp7)+0.34344×(e1C3O2)−0.45767×(c1C2C3)+0.7684×(CKetone)  d)

Equation a) relates a material's effectiveness in reducing the malodortrans-3-methyl-2-hexenoic acid (carboxylic acid based malodors)Equation b) relates a material's effectiveness in reducing the malodortrimethylamine (amine based malodors)Equation c) relates a material's effectiveness in reducing the malodor3-mercapto-3-methylhexan-1-ol (thiol based malodors)Equation d) relates a material's effectiveness in reducing the malodorskatole (indole based malodors)

-   2.) For purpose of the present application, a material's MORV is the    highest MORV value from equations 1.)a) through 1.)d).-   3.) If all MORV values from equations 1.)a) through 1.)d) above are    greater than 0.5, the subject material has a Universal MORV.

Method for Assigning Fragrance Fidelity Index (FFI) and the BlockerIndex (BI) for a Malodor Reduction Compound

Blocker materials suitable for use in consumer products of the presentinvention are chosen for their ability to decrease malodor, while notinterfering with perception of a fragrance. Material selection is doneby assigning two indices to a test sample material from two referencescales in order to rank odor strengths. The two reference scales are theFragrance Fidelity Index (FFI) scale and the Blocker Index (BI) scale.The FFI ranks the ability of the test sample material to impart aperceivable odor which could cause interference when combined withanother fragrance and the BI ranks the ability of the test samplematerial to reduce malodor perception. The two methods for assigning theindices to a test sample on the FFI and the BI reference scales aregiven below.

Method for Assigning the FFI to Test Samples

The first step in the method for assigning an FFI to the test samples onthe FFI reference scale is to create the FFI reference swatches. Theswatches for the scale are created by treating clean fabrics swatcheswith a known amount of a known concentration of an ethyl vanillinsolution. Fabric swatches for this test are white knit polycotton (4inch×4 inch) swatches from EMC ordered as PC 50/50. The supplier isinstructed to strip the swatches first, stripping involves washing twicewith a fragrance-free detergent and rinsing three times.

Making the FFI Reference Swatches

Make three solutions of ethyl vanillin using a 50%/50% EtOH/water as thediluent at the following concentrations: 25 ppm, 120 ppm and 1000 ppm.Pipette 13 μL of each of the three solutions into the middle of a cleanswatch resulting in about a 1 cm diameter of the solution in the middleof the swatch. This will create a sensory scale of three swatches withthree different odor levels based on the concentration of the solutionpipetted onto the swatch. After drying for 30 minutes in a vented hood,the swatches are wrapped in aluminum foil to prevent odor contaminationto the treated swatch. A clean untreated swatch is also included as thelowest anchor point of reference for odor strength on the FFI scale. TheFFI reference scale swatches should be used within 0.5 to 12 hours anddiscarded after 12 hours. The swatches are used as scale anchor pointswhen graders evaluate a test sample(s) and are assigned a FragranceFidelity Index (FFI) as show in Table 7.

At least four perfumers/expert graders are used to rank the ethylvanillin swatches in the FFI scale. The perfumer/expert grader needs todemonstrate adequate discrimination on the scale. The perfumer/expertpanel is asked to rank order swatches according to a scale between 0 and3. The panel must demonstrate statistical differences between theswatches as seen in Table 7.

TABLE 7 Results FFI of reference swatches from six perfumers/expertgraders. Expert Grader Std FFI Swatch 1 2 3 4 5 6 Ave Dev. 0 Control:stripped 0 0 0.5 0 0 0 0.08 0.2 swatch NIL ethyl vanillin 1 Strippedswatch with 0.5 0.5 0.5 1.5 0.5 1.0 0.75 0.4 13 μL 25 ppm ethyl vanillin2 Stripped swatch with 2.0 1.5 1.5 2.0 2.0 2.0 1.8 0.2 13 μL 120 ppmethyl vanillin 3 Stripped swatch with 3.0 2.0 3.0 3.0 3.0 3.0 2.8 0.4 13μL 1000 ppm ethyl vanillinThe expert graders must demonstrate a full range of 2.5 over the 4swatches to be acceptably discriminating. Grader 2 in table 1 has arange of only 2 and is eliminated from the panel. The panel of expertgraders must also demonstrated the ability to statistically discriminatebetween swatches in the scale.

TABLE 8 This table demonstrates acceptable expert graders with anacceptable range and the panel meets the requirement for discriminatingstatistics. Expert Grader Std FFI Swatch 1 3 4 5 6 Ave Dev. 0 Control:stripped 0 0.5 0 0 0 0.08 0.2 swatch NIL ethyl vanillin 1 Strippedswatch with 0.5 0.5 1.5 0.5 1.0 0.80 0.4 13 μL 25 ppm ethyl vanillin 2Stripped swatch with 2.0 1.5 2.0 2.0 2.0 1.9 0.2 13 μL 120 ppm ethylvanillin 3 Stripped swatch with 3.0 3.0 3.0 3.0 3.0 3.0 0.0 13 μL 1000ppm ethyl vanillinThe reference swatches represent the 0, 1, 2, and 3 FFIs on the FFIreference scale, Table 9. The expert grader should familiarize them selfwith the strength of the odor on the FFI reference swatches by sniffingeach one starting at 0 (the lowest odor strength) and ending at 3 (thehighest odor strength). This should be done prior to evaluating the testsample material treated swatch.

TABLE 9 Swatch treatments comprising the Fragrance Fidelity Index (FFI)reference scale Swatch treatment Conc. of ethyl vanillin FFI Cleanfabric swatch w/13 μL ethyl 1000 ppm ethyl vanillin 3 vanillin Cleanfabric swatch w/13 μL ethyl 120 ppm ethyl vanillin 2 vanillin Cleanfabric swatch w/13 μL ethyl 25 ppm ethyl vanillin 1 vanillin Cleanfabric swatch NIL ethyl vanillin NIL ethyl vanillin 0Making Swatches Treated with the Test Material

A clean swatch is treated with 13 μL of a known concentration of a testsample material resulting in an about 1 cm of the solution on the cleanswatch. Just like the reference swatches, the test sample materialswatch is dried in a vented hood for 30 minutes and then wrapped inaluminum foil to prevent contamination. The test material swatches andthe FFI reference swatches should be made within 2 hours of each other.The test material swatch must be used within 0.5 to 12 hours anddiscarded after 12 hours.

Assigning the FFI to the Test Material

At least two perfumers/expert graders are used to assign an FFI grade toa test sample. The perfumer/expert grader smells the test sample swatchby holding that swatch 1 inch from their nose with their nose centeredover the area where the test sample was pipetted on to the fabric andthen assigns the test sample an FFI grade using the FFI reference scaleanchor swatches as references. The test sample swatch is assigned an FPIgrade at or between numbers on the FFI scale shown in Table 9. In caseswhere the test sample material is graded greater than 3, the testmaterial is not a blocker material or the concentration of the materialneeds to be lowered and reevaluated to determine if a lower level has amalodor blocker functionality.

Method for Assigning the BI to Test Sample

The first step in the method for assigning a BI to a test samplematerial on the BI reference scale is to create the BI referenceswatches. The swatches for the scale are created by treating cleanfabrics swatches with a known amount of a known volume of isovalericacid solution at a known concentration. Fabric swatches for this testare white knit polycotton (4 inch×4 inch) swatches from EMC ordered asPC 50/50. The supplier is instructed to strip the swatches first,stripping involves washing twice with a fragrance-free detergent andrinsing three times.

Making the BI Reference Swatches

Make one solution of 0.08% isovaleric acid using 50%/50% EtOH/water asthe diluent. The BI scale contains one clean swatch with no malodorapplied. Three other swatches each have a different volume of the 0.08%isovaleric acid applied. Pipette 2 μL of the 0.08% isovaleric acidsolution to one clean swatch, 5 μL of the 0.08% isovaleric acid solutionto the next swatch and 20 μL of isovaleric acid to the final cleanswatch. These solutions are pipetted to the middle of the swatches. Thiswill create a sensory scale of three swatches with three different odorlevels based on the volume of the 0.08% isovaleric acid solutionpipetted onto the swatch. After drying for 30 minutes in a vented hood,the swatches are wrapped in aluminum foil to prevent odor contaminationto the treated swatch. A clean untreated swatch is also included as thelowest anchor point of reference for malodor strength on the BI scale.The BI reference scale swatches should be used within 0.5 to 12 hoursand discarded after 12 hours. The swatches are used as scale anchorpoints when graders evaluate a test sample(s) and are assigned a BlockerIndex (BI) as show in Table 12.

At least four perfumers/expert graders are used to rank the isovalericacid swatches in the BI scale. The perfumer/expert grader needs todemonstrate adequate discrimination on the scale. The perfumer/expertgrader is asked to rank order swatches according to a scale between 0and 3. The panel of graders must demonstrate statistical differencesbetween the swatches as seen in Table 10.

TABLE 10 Results from six perfumers/expert graders to create the BIscale. Expert Grader Std BI Swatch 1 2 3 4 5 Ave Dev. 0 Control:stripped swatch 0 0 0 0 0 0 0 NIL isovaleric acid 1 Stripped swatch with2 μL 0.5 2.0 1.0 1.0 0.5 1.0 0.5 0.08% isovaleric acid 2 Stripped swatchwith 5 μL 2.0 2.5 2.0 2.0 2.0 2.1 0.2 0.08% isovaleric acid 3 Strippedswatch with 20 μL 3.0 3.0 3.0 3.0 2.5 2.8 0.2 0.08% isovaleric acid

The expert graders must demonstrate a full range of 2.5 over the 4swatches to be acceptably discriminating. The panel of expert gradersmust also demonstrated the ability to statistically discriminate betweenswatches in the scale. Expert grader #2 did not demonstrate the abilityto discriminate between the swatches and is eliminated from the panel,see Table 11.

TABLE 11 This table demonstrates acceptable expert graders with anacceptable range and the panel meets the requirement for discriminatingstatistics. Expert Grader Std BI Swatch 1 3 4 5 Ave Dev. 0 Control:stripped swatch 0 0 0 0 0 0 NIL isovaleric acid 1 Stripped swatch with 2μL 0.5 1.0 1.0 0.5 0.8 0.3 0.08% isovaleric acid 2 Stripped swatch with5 μL 2.0 2.0 2.0 2.0 2.0 0 0.08% isovaleric acid 3 Stripped swatch with20 μL 3.0 3.0 3.0 2.5 2.9 0.2 0.08% isovaleric acid

The reference swatches represent the 0, 1, 2, and 3 BIs on the BIreference scale, Table 12. The expert grader should familiarizeshim/herself with the strength of the odor on the BI reference swatchesby sniffing each one starting at 0 (the lowest odor strength) and endingat 3 (the highest odor strength). This should be done prior toevaluating the swatch treated with the test material.

TABLE 12 Swatch treatments comprising the Blocker Index (BI) referencescale. Swatch/treatment Wt of isovaleric acid BI Clean fabric swatchw/20 μL 0.08% 16 mg isovaleric acid 3 isovaleric acid Clean fabricswatch w/5 μL 0.08% 4 mg isovaleric acid 2 isovaleric acid Clean fabricswatch w/2 μL 0.08% 1.6 mg isovaleric acid 1 isovaleric acid Cleanfabric swatch NIL isovaleric acid NIL isovaleric acid 0Making the Malodorous Swatch and Treating it with a Test Material

To evaluate the BI, the test material is applied to a malodorous swatchto determine how well the test material blocks the malodor. Themalodorous swatch is made by treating a clean swatch with 20 μL of a0.08% solution of isovaleric acid. Dry the malodorous swatch treatedwith isovaleric acid in a vented hood for 30 minutes. After drying themalodorous swatch a known concentration of test material solution,between 1 ppm and 100 ppm is pipetted onto the malodorous swatch. Applythe test material solution right on top of the spot where the isovalericacid solution was applied making an about 1 cm diameter spot. Just likethe BI reference swatches, the isovaleric acid+test material swatch isdried in a vented hood for 30 minutes and then wrapped in aluminum foilto prevent contamination. The isovaleric acid+test material swatches andthe BI reference swatches should be made within 2 hrs of each other. Theisovaleric acid+test material swatch must be used between 1-12 hoursjust like the reference swatches. It is sometimes necessary to evaluateseveral levels of the test material between about 1 and about 100 ppm todetermine the BI.

Assigning the BI to the Test Material

At least two perfumers/expert graders are used to assign the BI to thetest sample. The expert grader smells the isovaleric acid+test materialswatch by holding that swatch one inch from their nose with their nosecentered over the area where the test sample was pipetted on to thefabric and then assigns the isovaleric acid+test material swatch a BIbased on ranking its odor strength against the odor strength of theswatches in the BI reference scale. The test sample swatch is assigned aBI at or between numbers on the BI in table. In cases where theisovaleric acid+test material swatch odor is greater than 3 on the BIreference scale, this indicates the material is not a blocker or theconcentration of the test material needs to be lowered to achieve itsblocker functionality.

Malodor Reduction Compounds with FFI and BI Grades Based on theAforementioned

Table Ref # CAS# log P Name Conc FFI BI 281 54830-99-8 3.113a,4,5,6,7,7a-hexahydro-4,7- 10 ppm 0 2.0 methano-1H-indenyl acetate 50ppm 0.5 2.0 677 139504-68-0 3.75 1-((2-(tert- 10 ppm 0 2.3butyl)cyclohexyl)oxy)butan-2-ol 50 ppm 1.8 2.0 962 55066-48-3 3.173-methyl-5-phenylpentan-1-ol 10 ppm 0 2.3 50 ppm 0.5 1.7 261 173445-65-33.29 3-(3,3-dimethyl-2,3-dihydro-1H- 10 ppm 0 1.8 inden-5-yl)propanal 50ppm 1.3 1.3 1139 87731-18-8 2.11 (Z)-cyclooct-4-en-1-yl methyl 10 ppm 02.0 carbonate 50 ppm 1.0 2.7 4430-31-3 1.433,4,4a,5,6,7,8,8a-octahydrochromen- 10 ppm 0 2.0 2-one 50 ppm 0 2.0 20440379-24-6 3.89 7-methyloctyl acetate 10 ppm 0 2.0 50 ppm 0 2.7 100593981-50-1 5.59 ethyl (2,3,6-trimethylcyclohexyl) 50 ppm 0.5 2.6carbonate 391 106-33-2 5.73 Ethyl laurate 50 ppm 0.3 2.2 1148 1139-30-64.06 Caryophyllene Oxide 50 ppm 0.5 2.3 524 13877-91-3 4.313,7-Dimethyl-1,3,6-Octatriene(cis-β 50 ppm 0 2.8 3338-55-4 ocimene 70%)1149 23787-90-8 4 1,3,4,6,7,8alpha-hexahydro- 10 ppm 0 1.51,1,5,5-tetramethyl-2H-2,4alpha- 50 ppm 0.8 2.3 methanophtalen-8(5H)-one112-42-5 4.62 Undecanol 50 ppm 0.8 2.3 174 112-53-8 5.17 1-dodecanol 50ppm 0.5 2.3 98-52-2 2.78 4-tert-butyl cyclohexane 10 ppm 0 2.0 50 ppm0.3 2.0 109 112-39-0 6.41 Methyl palmitate 10 ppm 2.0Malodor Control Compounds with Improved Performance at Lower Levels.

Below are some non-limiting examples of preferred behavior by which themalodor control compound gives improved malodor control at lowerconcentration. These nonlimiting data provide additional compelling datathat malodor is being blocked, not masked.

Table Ref # CAS# Name Conc FFI BI N/A 68912-13-08,8-dimethyl-3a,4,5,6,7,7a- 10 ppm 0 1.5 hexahydro-1H-4,7- 50 ppm 0 2.2methanoinden-6-yl propionate N/A TBD 4,8-dimethyl-1-(methylethyl)- 10ppm 2.0 7-oxybiciclo [4.3.0]nonane 50 ppm 0.3 2.2

Retesting Malodor Reduction Compounds at Lower Levels.

The example below demonstrates that while a malodor control compoundcould fail to demonstrate odor blocking (BI>2.5) at a higherconcentration it should be retested at a lower concentration todetermine if it passes.

Table Ref # CAS # Name Conc FFI BI N/A 173445-65-3 1H-Indene-5-propanal,2,3- 10 ppm 0 1.5 dihydro-3,3-dimethyl- 50 ppm 0.5 2.7

Example 1 Compositions Comprising Malodor Reduction Compounds

In the present invention blends enable more potent malodor reductionbecause blends are useful at a higher % of the product compositionbefore becoming olfactively noticeable. Below are non-limiting examplesof malodor reduction compounds.

% wt Active Component CAS# A B C D E 2,2,8,8-tetramethyl-octahydro-1H-29461-14-1 35-45 15-25  5-20 10-30 15-25 2,4a-methanonapthalene-10-one1H-Indene-ar-propanal, 2,3- 300371-33-9 10-20  1-30 NIL  5-10 1-5dihydro-1,1-dimethyl- Hexadecanoic acid, (2E)-3,7- 3681-73-0 35-45 10-25NIL 30-40 35-50 dimethyl-2,6-octadien-1-yl ester1-Pentanol-3-methyl-5-phenyl 55066-48-3 10-20 10-25  2-10  5-17 104,7-Methano-1H-inden-5-ol, 171102-41-3 0-5 10-25 NIL 1-6 1-543a,4,5,6,7,7a-hexahydro-, 5-acetate 4,8-dimethyl-1-(methylethyl)-7- N/A0-5 NIL NIL NIL 1-5 oxybiciclo [4.3.0]nonane(3Z)-3,7-dimethylocta-1,3,6-triene 3338-55-4 NIL NIL 10-20 2-5 NIL1H-Indene-5-propanal, 2,3- 173445-65-3 NIL NIL NIL 7.5-16   1-15dihydro-3,3-dimethyl- 3,4,4a,5,6,7,8,8a- 4430-31-3 NIL NIL NIL 3-7  1-15octahydrochromen-2-one 1-(2-tert- 139504-68-0 NIL NIL NIL 0.25-1.5  NILbutylcyclohexyl)oxybutan-2-ol ethyl (2,3,6-trimethylcyclohexyl)93981-50-1 NIL NIL 15-30 NIL  2 carbonate benzyl 2-hydroxypropanoate2051-96-9 NIL NIL 2-5 NIL NIL (3,5-dimethylcyclohex-3-en-1- 67634-16-6NIL NIL  5-30 NIL NIL yl)methanol 2-Dodecanol 10203-28-8 NIL 0.25-1  NIL 0.5-3  NIL

Example 2 Compositions Comprising Malodor Reduction Compounds

% wt Active Ingredient CAS # A B C B D E (E)-1-(2,6,6-trimethyl-1-127-42-4 4 8 2 8 3 2 cyclohex-2-enyl)pent-1-en-3- one ethyl dodecanoate106-33-2 NIL 1 NIL 3 NIL NIL 3a,4,5,6,7,7a-hexahydro-1H- 68912-13-0 8 301 4 1 3.5 4,7-methanoinden-1-yl propanoate [1R-(1R*,4R*,6R*,10S*)]-1139-30-6 NIL 0.3 2 0.5 NIL 0.5 4,12,12-trimethyl-9- methylene-5-oxatricyclo[8.2.0.04,6]dodecane (8E)-cyclohexadec-8-en-1-one 3100-36-5NIL 5 NIL 7 NIL NIL 3,5,5-trimethylhexyl acetate 58430-94-7 25  15 50 35 60  56 ethyl (2,3,6- 93981-50-1 NIL 1 NIL 5 NIL NILtrimethylcyclohexyl) carbonate 2,4-dimethyl-4,4a,5,9b- 27606-09-3 25  1015  15 16  15 tetrahydroindeno[1,2- d][1,3]dioxine 2,2,7,7- 23787-90-8 89 5 7 5 5 tetramethyltricyclo[6.2.1.01,6] undecan-5-one(3,5-dimethylcyclohex-3-en- 67634-16-6 NIL 0.7 NIL 0.5 NIL NIL1-yl)methanol 3-(7,7-dimethyl-4- 33885-52-8 30  20 25  15 15  18bicyclo[3.1.1]hept-3-enyl)- 2,2-dimethylpropanal Total 100  100 100  100100  100

Example 3 Malodor Reduction Composition

% wt Active Ingredient CAS # A B C 5-Cyclohexadecen-1-One 37609-25-915.0 2.00 2.00 decahydro-2,2,7,7,8,9,9- 476332-65-7 0.005 0.01 0.01heptamethylindeno(4,3a-b)furan 2,3-Dihydro-5,6-dimethoxy-2-(4-33704-61-9 0.3 0.5 0.5 piperidinylmethylene)-1H-inden-1-one (Wrong name)Cedryl Methyl Ether 19870-74-7 6.0 10.0 4.0 Trans-4-Decenal 65405-70-10.005 0.002 0.002 Decyl Aldehyde 112-31-2 3.74 2.0 2.0 3-methylcyclopentadecenone 63314-79-4 0.4 1.0 1.0 Diphenyl Oxide 101-84-8 0.51.0 1.0 3a,4,5,6,7,7a-hexahydro-4,7-methano- 54830-99-8 5.0 8.0 8.01H-indenyl acetate 3a,4,5,6,7,7a-hexahydro-1H-4,7- 68912-13-0 6.0 8.08.0 methanoinden-1-yl propanoate 2-(5-methyl-2-propan-2-yl-8- 68901-32-610.0 15.0 15.0 bicyclo[2.2.2]oct-5-enyl)-1,3-dioxolane(E)-3,7-dimethyl-2,6- 3681-73-0 10.0 10.0 16.0 octadienylhexadecanoateIso Nonyl Acetate 58430-94-7 6.65 8.0 3.0 2,2,7,7- 23787-90-8 10.0 8.08.0 tetramethyltricyclo[6.2.1.01,6]undecan-5- one (1-Methyl-2-(1,2,2-198404-98-7 0.1 0.3 0.3 trimethylbicyclo[3.1.0]-hex-3-ylmethyl)cyclopropyl)methanol Lauric Aldehyde 112-54-9 0.625 1.0 0.7Methyl Iso Eugenol 93-16-3 18.000 10.0 13.0 Methyl hexadecanoate112-39-0 3.000 10.0 12.0 2,3-dihydro-1,1-1H-dimethyl-indene-ar-300371-33-9 0.400 0.0 0.3 propanal 4-tert-butylcyclohexanol 98-52-20.400 0.1 0.1 2-isobutyl-4-hydroxy-4- 63500-71-0 1.600 2.0 2.0methyltetrahydropyran Undecyl Aldehyde 112-44-7 1.725 2.888 1.888Undecylenic Aldehyde 112-45-8 0.550 0.2 1.2 Total 100 100.0 100.0

Example 4 Free Flowing Particles that Comprise Malodor ReductionMaterials

Examples of free flowing particles products that comprise malodorreduction materials and/or compositions either free or in microcapsuleor combinations thereof. The table below also exemplifies combinationswhich comprise also perfume free and in microcapsules or combinations ofthese with aforementioned combinations with malodor reduction materialsand/or compositions. The table also exemplifies compositions having onlymalodor reduction materials and/or compositions free, in microcapsulesand combinations thereof that have little to no fragrance to provide aproduct that is essentially ‘fragrance free’ The examples below compriseat least one malodor reduction compound or composition either free or ina microcapsule

% wt Active Ingredients A B C D Polyethylene glycol 70-99  0-20 0-29 0-40 Clay 0-29 0-20 0-20  0-10 NaCl 0-29 50-99  0-29  0-40 Na2SO4 0-100-10 0-10 0-5 Urea 0-29 0-29 0-99  0-40 Polysaccharide 0-29 0-29 0-290-5 Zeolite 0-29 0-29 0-29 0-5 Plasticizers/Solvents Starch/Zeolite 0-290-29 0-29 0-5 Silica 0-5  0-5  0-5  0-5 Metal oxide 0-29 0-29 0-29  0-29Metal catalyst 0.001-0.5   0.001-0.5   0.001-0.5   0.001-0.5  Opacifier0-5  0-5  0-1  0-1 Water 0-2  0-2  0-5  0-5 Perfume 0-5  0-5  0-5  0-5Perfume in delivery system¹⁰ 0-10  0-4.5 0-3   0-7.5 Malodor reductionmaterials/ compositions MORV material Table 1. Number 677 0-10 0-10 0-10 0-10 CAS # 139504-68-0 Malodor reduction comp. EXAMPLE 1 0-5  0-5  0-5 0-5 Malodor reduction comp. EXAMPLE 2 0-20 0-20 0-20 0-5 Malodorreduction comp. EXAMPLE 3 0-12 0-12 0-12  0-20 Malodor reductioncomposition in 0-10 0-10 0-10 0-5 delivery system¹⁰: Perfume + malodorreduction composition in delivery system¹⁰ (1) PEG (2) Clay (3) Urea (4)Polysaccharide, mostly starches, unmodified starches, starchderivatives, acid-modified starch and kappa carrageenan (5) Zeolite (6)Starch/Zeolite - SEA (7) Metal oxides - non-limiting examples - TiO2,ZnO, MnO (8) Metal catalysts (9) Opacifier ¹⁰Delivery system caninclude, Polymer-Assisted delivery, Molecular Assisted delivery,Cyclodextrin delivery Starch encapsulated delivery, Zeolite and/orinorganic delivery system.

Example 5 Spray-Dried Laundry Detergent Powder Composition with MalodorReduction Materials and Process of Making it

An example of a Spray-Dried Laundry Detergent Powder compositionprepared with malodor reduction composition, according to thecompositions shown in EXAMPLES 1-3.

wt % Active Ingredients A B C D Linear alkyl benzene sulfonate 10.6 15.821.3 35.7 Acrylate/maleate copolymer 4.6 6.8 9.4 14.2 Ethylenediamedisuccinic acid and/or 1.4 2.1 1.7 2.9 Hydroxyethane dimethylenephosphonic acid Sodium carbonate 19.4 26.5 18.8 29.9 Sodium sulfate 28.642.4 — — Carboxy methyl cellulose polymer — — 4.3 7.1 Carboxy methylcellulose polymer — — 4.3 7.1 Miscellaneous, such as magnesium sulfate,1.4 2.2 2.5 4.2 brightener and one or more stabilizers Perfume Perfume0-3 0-2 0-2 0-3 Perfume in delivery system¹ 0-5 0-5 0-5 0-5 Malodorreduction materials/compositions MORV material Table 1. Number 677 0.005to 0.05 0.005 to 0.05 0.005 to 0.05 0.005 to 0.05 CAS # 139504-68-0Malodor reduction composition EXAMPLE 1 0.0025 to 0.015 0.0025 to 0.0150.0025 to 0.015 0.0025 to 0.015 Malodor reduction composition EXAMPLE 2 0.004 to 0.035  0.004 to 0.035  0.004 to 0.035  0.004 to 0.035 Malodorreduction composition EXAMPLE 3 0.01 to 0.5 0.01 to 0.5 0.01 to 0.5 0.01to 0.5 Malodor reduction composition in delivery 0-2 0-2 0-2 0-2 system¹Perfume + malodor reduction composition 0-5 0-5 0-5 0-5 in Deliverysystem¹ Water Balance Balance Balance Balance ¹Delivery system caninclude, Polymer-Assisted delivery, Molecular Assisted delivery,Cyclodextrin delivery, Starch encapsulated delivery, Zeolite and/orinorganic delivery system

Preparation of Spray-Dried Laundry Detergent Powders.

Aqueous slurry a having the composition as described above is preparedhaving a moisture content of 34.0%. Any ingredient added above in liquidform is heated to 70° C., such that the aqueous slurry is never at atemperature below 70° C. At the end of preparation, the aqueous slurryis heated to 80° C. and pumped under pressure (5×10⁶ Nm⁻²), into acounter current spray-drying tower with an air inlet temperature of from290° C. The aqueous slurry is atomized and the atomized slurry is driedto produce a solid mixture, which is then cooled and sieved to removeoversize material (>1.8 mm) to form a spray-dried powder, which isfree-flowing. Fine material (<0.15 mm) is elutriated with the exhaustthe exhaust air in the spray-drying tower and collected in a post towercontainment system. The spray-dried powder a has a moisture content of2.0 wt %, a bulk density of 310 g/l and a particle size distributionsuch that greater than 90 wt % of the spray-dried powder has a particlesize of from 150 to 710 micrometers. The composition of the spray-driedpowder A is listed in the table above. Perfume and malodor reductioncomposition are sprayed onto the composition following the spray dryprocedure.

Aqueous slurry b having the composition as described above is preparedhaving a moisture content of 42.0%. Any ingredient added above in liquidform is heated to 70° C., such that the aqueous slurry is never at atemperature below 70° C. At the end of preparation, the aqueous slurryis heated to 85° C. and pumped under pressure (from 6.5×10⁶ Nm⁻²), intoa counter current spray-drying tower with an air inlet temperature offrom 275° C. The aqueous slurry is atomized and the atomized slurry isdried to produce a solid mixture, which is then cooled and sieved toremove oversize material (>1.8 mm) to form a spray-dried powder b, whichis free-flowing. Fine material (<0.15 mm) is elutriated with the exhaustthe exhaust air in the spray-drying tower and collected in a post towercontainment system. The spray-dried powder has a moisture content of 3.0wt %, a bulk density of 250 and a particle size distribution such thatgreater than 90 wt % of the spray-dried powder has a particle size offrom 150 to 710 micrometers. The composition of the spray-dried powderis given in the table above. Perfume and malodor reduction compositionare sprayed onto the composition after the spray dry process.

The dimensions and values disclosed herein are not to be understood asbeing strictly limited to the exact numerical values recited. Instead,unless otherwise specified, each such dimension is intended to mean boththe recited value and a functionally equivalent range surrounding thatvalue. For example, a dimension disclosed as “40 mm” is intended to mean“about 40 mm.”

Every document cited herein, including any cross referenced or relatedpatent or application is hereby incorporated herein by reference in itsentirety unless expressly excluded or otherwise limited. The citation ofany document is not an admission that it is prior art with respect toany invention disclosed or claimed herein or that it alone, or in anycombination with any other reference or references, teaches, suggests,or discloses any such invention. Further, to the extent that any meaningor definition of a term in this document conflicts with any meaning ordefinition of the same term in a document incorporated by reference, themeaning or definition assigned to that term in this document shallgovern.

While particular embodiments of the present invention have beenillustrated and described, it would be obvious to those skilled in theart that various other changes and modifications can be made withoutdeparting from the spirit and scope of the invention. It is, therefore,intended to cover in the appended claims all such changes andmodifications that are within the scope of this invention.

What is claimed:
 1. A product, said product comprising: a) a sum totalfrom about 0.001% to about 20% of 1 to about 30 malodor reductionmaterials having a Blocker Index of less than 3 or a Blocker Indexaverage of 3 to about 0.001; b) a carrier that is a solid at 25° C.; andc) optionally, 0.5% to about 50% of an enzyme stable polymer.
 2. Aproduct according to claim 1, wherein said malodor reduction materialshave a Fragrance Fidelity Index of from about Fragrance Fidelity Indexof less than
 3. 3. A product according to claim 1, comprising a perfume.4. A product according to claim 3, said composition comprising a weightratio of parts of malodor reduction composition to perfume of from about1:20,000 to about 3000:1.
 5. A product according to claim 1 wherein saidone or more malodor reduction materials are selected from the groupconsisting of (E)-3,7-dimethylocta-2,6-dien-1-yl palmitate;1-((2-(tert-butyl)cyclohexyl)oxy)butan-2-ol;2-(8-isopropyl-6-methylbicyclo[2.2.2]oct-5-en-2-yl)-1,3-dioxolane;2,2,6,6,7,8,8-heptamethyldecahydro-2H-indeno[4,5-b]furan;2,3-dihydro-1,1-1H-dimethyl-indene-ar-propanal;(R,Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)pent-1-en-3-one;3-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2,2-dimethylpropanal;(Z)-cyclooct-4-en-1-yl methyl carbonate; ethyl dodecanoate;(Z)-3,7-dimethylocta-1,3,6-triene; (E)-3,7-dimethylocta-1,3,6-trieneCis-ocimene); 3a-isopropyl-2,6-dimethyloctahydrobenzofuran; 1,3,4,6,7,8alpha-hexahydro-1,1,5,5-tetramethyl-2H-2,4alpha-methanophthalen-8(5H)-one;3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoind3en-1-yl propanoate;(E)-cyclohexadec-5-en-1-one;(1-methyl-2-((1,2,2-trimethylbicyclo[3.1.0]hexan-3-yl)methyl)cyclopropyl)methanol;(E)-oxacyclohexadec-13-en-2-one; (E)-dec-4-enal;(E)-1,1-dimethoxy-3,7-dimethylocta-2,6-diene;1,1,2,3,3-pentamethyl-1,2,3,5,6,7-hexahydro-4H-inden-4-one;oxydibenzene; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl acetate;3-methyl-5-phenylpentan-1-ol;3-(3,3-dimethyl-2,3-dihydro-1H-inden-5-yl)propanal;3,4,4a,5,6,7,8,8a-octahydrochromen-2-one; 7-methyloctyl acetate;3,5,5-trimethyl hexyl acetate;4,5-epoxy-4,11,11-trimethyl-8-methylenebicyclo(7.2.0)undecane;8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-ylpropionate; 1-(5,5-dimethylcyclohex-1-en-1-yl)pent-4-en-1-one;cis-6-nonen-1-ol; 2-isopropyl-5-methylphenol;2,6-di-tert-butyl-4-methylphenol and mixtures thereof.
 6. A productaccording to claim 1, wherein said malodor reduction materials are notselected from the group consisting of geranyl nitrile; helional;nonanal; linalool; (S)-(+)-linalool; (R)-(−)-linalool; nerol;tetrahydrolinalool; 2-phenylethyl acetate; eugenol; ethyl linalool;allyl heptoate; agrumen nitrile; citronitrile;2,2-dimethyl-3-(m-tolyl)propan-1-ol; 2-methyl-5-phenylpentan-1-ol;dodecanenitrile; 2-heptylcyclopentan-1-one; methyl nonyl acetaldehyde;3-(2-ethylphenyl)-2,2-dimethylpropanal;(Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-en-1-one;(R,E)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol;4-(tert-butyl)cyclohexyl acetate; 1-cyclohexylethyl (E)-but-2-enoate;allyl 2-(cyclohexyloxy)acetate; alpha terpinyl acetate; beta terpinylacetate; gamma terpinyl acetate; methyl dodecyl ether;2,4-dimethyl-4,4a,5,9b-tetrahydroindeno[1,2-d][1,3]dioxine; cinnamylisobutyrate;(E)-2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-2-enal; gammamethyl ionone; ethyl 2,3,6-trimethyl cyclohexyl carbonate ethyl2,3,6-trimethyl cyclohexyl carbonate; Citral diethyl acetal;Dimethoxycyclododecane;1((2S,3S)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-yl)ethan-1-one;oxacyclohexadecan-2-one;4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopenta[g]isochromene;Ethylene brassylate; Methyl(Z)-2-((3-(4-(tert-butyl)phenyl)-2-methylpropylidene)amino)benzoate;4,7-Methano-1H-inden-5-ol, 3a,4,5,6,7,7a-hexahydro-, 5-acetate; cedrylmethyl ether; vetivert acetate;1-((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-methanoazulen-5-yl)ethan-1-one;Benzophenone; Farnesol; trans,trans-farnesol;3-(3-isopropylphenyl)butanal; 2,6,10-trimethylundec-9-enal;3-(4-(tert-butyl)phenyl)propanal;3-(4-isopropylphenyl)-2-methylpropanal; Citronellal (1); Citronellal(d); (E)-4,8-dimethyldeca-4,9-dienal; Pino Acetaldehyde;3-(4-(tert-butyl)phenyl)-2-methylpropanal; Cinnamic aldehyde; Citral;Geranial; MethoxyMelonal; o-methoxycinnamaldehyde;(E)-4-((3aS,7aS)-octahydro-5H-4,7-methanoinden-5-ylidene)butanal; MethylOctyl Acetaldehyde; 3-(4-methoxyphenyl)-2-methylpropanal;5-methoxyoctahydro-1H-4,7-methanoindene-2-carbaldehyde; Iso Cyclocitral;Octanal; 2-Undecenal; 10-Undecenal; Trans-trans-2,6-Nonadienal;Trans-2,cis-6-nondienal; Heliotropin; Hexyl Cinnamic aldehyde;p-methyl-alpha-pentylcinnamaldehyde; Alpha-methyl cinnamaldehyde;3,4-dimethoxybenzaldehyde; Myrtenal; Perillaldehyde; Maceal; Methylpalmitate; Methyl iso eugenol and mixtures thereof.
 7. A productaccording to claim 1, said product comprising an additional materialthat is an adjunct ingredient selected from the group consisting ofsurfactants, builders, chelating agents, dye transfer inhibiting agents,dispersants, enzymes, and enzyme stabilizers, catalytic materials,bleach activators, a fabric softener active, hydrogen peroxide, sourcesof hydrogen peroxide, preformed peracids, polymeric dispersing agents,clay soil removal/anti-redeposition agents, brighteners, sudssuppressors, dyes, hueing dyes, perfumes, perfume delivery systems,structure elasticizing agents, carriers, structurants, hydrotropes,processing aids, solvents, pigments and mixtures thereof.
 8. A method ofcontrolling malodors comprising: contacting a situs comprising a malodorand/or a situs that will become malodorous with the product of claim 1.9. The method of claim 8 wherein, said situs comprises a fabric and saidcontacting step comprises contacting said fabric with a sufficientamount of the product of claim 1 to provide said fabric with a level ofmalodor reduction material at least 0.001 mg of malodor reductionmaterial/kg of fabric.